Stretchable, self-healable, and photodegradable supercapacitor based on a polyelectrolyte crosslinked via dynamic host-guest interaction

Jaeik Kim; Jung Wook Kim; Somin Kim; Kayeon Keum; Junyoung Park; Yu Ra Jeong; Sang Woo Jin; Jeong Sook Ha

doi:10.1016/j.cej.2021.130121

Stretchable, self-healable, and photodegradable supercapacitor based on a polyelectrolyte crosslinked via dynamic host-guest interaction

Jaeik Kim
, Jung Wook Kim
, Somin Kim
, Kayeon Keum
, Junyoung Park
, Yu Ra Jeong
, Sang Woo Jin
, Jeong Sook Ha^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

We report on the fabrication of a high performance multi-functional supercapacitor which is intrinsically stretchable, self-healable, and photodegradable. A repeatedly stretchable (500 times), photodegradable hydrogel that self-heals quickly at room temperature without any trigger is synthesized by crosslinking of azobenzeno-polyacrylamide (Azo-PAM) and water-soluble α-cyclodextrin polymer (α-CDP) via dynamic host-guest interaction. With the Azo-PAM/α-CDP/LiCl hydrogel as polyelectrolyte, the stretchable, self-healable, and photodegradable supercapacitor is fabricated. After complete bisection, the supercapacitor recovers its electrochemical performance by physical contact in air-ambient conditions and maintains its performance upon multiple cycles of self-healing at a single bisected location. It also maintains elastic performance even after repeated stretching and self-healing. Finally, the supercapacitor exhibits photodegrading performance, dissolving in water upon UV-irradiation after use. This work demonstrates the superior performance and high potential of our newly devised stretchable, self-healable, and photodegradable supercapacitor as a smart energy storage device for next-generation durable and eco-friendly wearable electronics.

Original language	English
Article number	130121
Journal	Chemical Engineering Journal
Volume	422
DOIs	https://doi.org/10.1016/j.cej.2021.130121
Publication status	Published - 2021 Oct 15

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (Grant No. NRF-2019R1A2B5B03069545 ). The authors also thank the KU-KIST graduate school program of Korea University.

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (Grant No. NRF-2019R1A2B5B03069545). The authors also thank the KU-KIST graduate school program of Korea University.

Publisher Copyright:
© 2021 Elsevier B.V.

Keywords

Host-guest interaction
Photodegradable
Self-healable
Stretchable
Supercapacitor

ASJC Scopus subject areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1016/j.cej.2021.130121

Cite this

@article{4648518136a24016b76ed03d8bd1795b,

title = "Stretchable, self-healable, and photodegradable supercapacitor based on a polyelectrolyte crosslinked via dynamic host-guest interaction",

abstract = "We report on the fabrication of a high performance multi-functional supercapacitor which is intrinsically stretchable, self-healable, and photodegradable. A repeatedly stretchable (500 times), photodegradable hydrogel that self-heals quickly at room temperature without any trigger is synthesized by crosslinking of azobenzeno-polyacrylamide (Azo-PAM) and water-soluble α-cyclodextrin polymer (α-CDP) via dynamic host-guest interaction. With the Azo-PAM/α-CDP/LiCl hydrogel as polyelectrolyte, the stretchable, self-healable, and photodegradable supercapacitor is fabricated. After complete bisection, the supercapacitor recovers its electrochemical performance by physical contact in air-ambient conditions and maintains its performance upon multiple cycles of self-healing at a single bisected location. It also maintains elastic performance even after repeated stretching and self-healing. Finally, the supercapacitor exhibits photodegrading performance, dissolving in water upon UV-irradiation after use. This work demonstrates the superior performance and high potential of our newly devised stretchable, self-healable, and photodegradable supercapacitor as a smart energy storage device for next-generation durable and eco-friendly wearable electronics.",

keywords = "Host-guest interaction, Photodegradable, Self-healable, Stretchable, Supercapacitor",

author = "Jaeik Kim and Kim, \{Jung Wook\} and Somin Kim and Kayeon Keum and Junyoung Park and Jeong, \{Yu Ra\} and Jin, \{Sang Woo\} and Ha, \{Jeong Sook\}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (Grant No. NRF-2019R1A2B5B03069545 ). The authors also thank the KU-KIST graduate school program of Korea University. Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (Grant No. NRF-2019R1A2B5B03069545). The authors also thank the KU-KIST graduate school program of Korea University. Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2021",

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doi = "10.1016/j.cej.2021.130121",

language = "English",

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AU - Kim, Jaeik

AU - Kim, Jung Wook

AU - Kim, Somin

AU - Keum, Kayeon

AU - Park, Junyoung

AU - Jeong, Yu Ra

AU - Jin, Sang Woo

AU - Ha, Jeong Sook

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (Grant No. NRF-2019R1A2B5B03069545 ). The authors also thank the KU-KIST graduate school program of Korea University. Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (Grant No. NRF-2019R1A2B5B03069545). The authors also thank the KU-KIST graduate school program of Korea University. Publisher Copyright: © 2021 Elsevier B.V.

PY - 2021/10/15

Y1 - 2021/10/15

N2 - We report on the fabrication of a high performance multi-functional supercapacitor which is intrinsically stretchable, self-healable, and photodegradable. A repeatedly stretchable (500 times), photodegradable hydrogel that self-heals quickly at room temperature without any trigger is synthesized by crosslinking of azobenzeno-polyacrylamide (Azo-PAM) and water-soluble α-cyclodextrin polymer (α-CDP) via dynamic host-guest interaction. With the Azo-PAM/α-CDP/LiCl hydrogel as polyelectrolyte, the stretchable, self-healable, and photodegradable supercapacitor is fabricated. After complete bisection, the supercapacitor recovers its electrochemical performance by physical contact in air-ambient conditions and maintains its performance upon multiple cycles of self-healing at a single bisected location. It also maintains elastic performance even after repeated stretching and self-healing. Finally, the supercapacitor exhibits photodegrading performance, dissolving in water upon UV-irradiation after use. This work demonstrates the superior performance and high potential of our newly devised stretchable, self-healable, and photodegradable supercapacitor as a smart energy storage device for next-generation durable and eco-friendly wearable electronics.

AB - We report on the fabrication of a high performance multi-functional supercapacitor which is intrinsically stretchable, self-healable, and photodegradable. A repeatedly stretchable (500 times), photodegradable hydrogel that self-heals quickly at room temperature without any trigger is synthesized by crosslinking of azobenzeno-polyacrylamide (Azo-PAM) and water-soluble α-cyclodextrin polymer (α-CDP) via dynamic host-guest interaction. With the Azo-PAM/α-CDP/LiCl hydrogel as polyelectrolyte, the stretchable, self-healable, and photodegradable supercapacitor is fabricated. After complete bisection, the supercapacitor recovers its electrochemical performance by physical contact in air-ambient conditions and maintains its performance upon multiple cycles of self-healing at a single bisected location. It also maintains elastic performance even after repeated stretching and self-healing. Finally, the supercapacitor exhibits photodegrading performance, dissolving in water upon UV-irradiation after use. This work demonstrates the superior performance and high potential of our newly devised stretchable, self-healable, and photodegradable supercapacitor as a smart energy storage device for next-generation durable and eco-friendly wearable electronics.

KW - Host-guest interaction

KW - Photodegradable

KW - Self-healable

KW - Stretchable

KW - Supercapacitor

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DO - 10.1016/j.cej.2021.130121

M3 - Article

AN - SCOPUS:85105029299

SN - 1385-8947

VL - 422

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

M1 - 130121

ER -

Stretchable, self-healable, and photodegradable supercapacitor based on a polyelectrolyte crosslinked via dynamic host-guest interaction

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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