Structural and Piezoelectric Properties of (1-x)Pb(Zr1-yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 Ceramics Near Triple Point

Joon Hur; Jong Hyun Kim; Tae Gon Lee; In Tae Seo; Dae Hyeon Kim; Sahn Nahm; Chong Yun Kang

doi:10.1111/jace.13687

Structural and Piezoelectric Properties of (1-x)Pb(Zr_1-yTi_y)O₃-xPb(Zn_0.4Ni_0.6)_1/3Nb_2/3O₃ Ceramics Near Triple Point

Joon Hur
, Jong Hyun Kim
, Tae Gon Lee
, In Tae Seo
, Dae Hyeon Kim
, Sahn Nahm^*
, Chong Yun Kang

^*Corresponding author for this work

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The crystal structure and piezoelectric properties of (1-x)Pb(Zr_1-yTi_y)O₃-xPb(Zn_0.4Ni_0.6)_1/3Nb_2/3O₃ [(1-x)PZ_1-yT_y-xPZNN] ceramics were investigated. The 0.665PZ_0.45T_0.55-0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d₃₃ and k_p values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large ε^T₃₃/ε_o value of 3250. Although the maximum d₃₃ value was obtained from the triple point composition specimen, its g₃₃ and d₃₃ × g₃₃ values were relatively small because of its large ε^T₃₃/ε_o value. However, the 0.665PZ_0.46T_0.54-0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g₃₃ value of 43 × 10^-3 Vm/N and a d₃₃ × g₃₃ value of 27 000 × 10^-15m²/N. Therefore, this ceramic is a good candidate for multilayer actuators and piezoelectric energy harvesters.

Original language	English
Pages (from-to)	2887-2893
Number of pages	7
Journal	Journal of the American Ceramic Society
Volume	98
Issue number	9
DOIs	https://doi.org/10.1111/jace.13687
Publication status	Published - 2015 Sept 1

Bibliographical note

Publisher Copyright:
© 2015 The American Ceramic Society.

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

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10.1111/jace.13687

Cite this

@article{004bec71857145c0870f359572428945,

title = "Structural and Piezoelectric Properties of (1-x)Pb(Zr1-yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 Ceramics Near Triple Point",

abstract = "The crystal structure and piezoelectric properties of (1-x)Pb(Zr1-yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1-x)PZ1-yTy-xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55-0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54-0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10-3 Vm/N and a d33 × g33 value of 27 000 × 10-15m2/N. Therefore, this ceramic is a good candidate for multilayer actuators and piezoelectric energy harvesters.",

author = "Joon Hur and Kim, \{Jong Hyun\} and Lee, \{Tae Gon\} and Seo, \{In Tae\} and Kim, \{Dae Hyeon\} and Sahn Nahm and Kang, \{Chong Yun\}",

note = "Publisher Copyright: {\textcopyright} 2015 The American Ceramic Society.",

year = "2015",

month = sep,

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doi = "10.1111/jace.13687",

language = "English",

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T1 - Structural and Piezoelectric Properties of (1-x)Pb(Zr1-yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 Ceramics Near Triple Point

AU - Hur, Joon

AU - Kim, Jong Hyun

AU - Lee, Tae Gon

AU - Seo, In Tae

AU - Kim, Dae Hyeon

AU - Nahm, Sahn

AU - Kang, Chong Yun

PY - 2015/9/1

Y1 - 2015/9/1

N2 - The crystal structure and piezoelectric properties of (1-x)Pb(Zr1-yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1-x)PZ1-yTy-xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55-0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54-0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10-3 Vm/N and a d33 × g33 value of 27 000 × 10-15m2/N. Therefore, this ceramic is a good candidate for multilayer actuators and piezoelectric energy harvesters.

AB - The crystal structure and piezoelectric properties of (1-x)Pb(Zr1-yTiy)O3-xPb(Zn0.4Ni0.6)1/3Nb2/3O3 [(1-x)PZ1-yTy-xPZNN] ceramics were investigated. The 0.665PZ0.45T0.55-0.335PZNN ceramic has the triple point composition, where the rhombohedral, pseudocubic, and tetragonal structures coexist. Maximum d33 and kp values of 770 pC/N and 0.69, respectively, were observed from this specimen; it also exhibited a large εT33/εo value of 3250. Although the maximum d33 value was obtained from the triple point composition specimen, its g33 and d33 × g33 values were relatively small because of its large εT33/εo value. However, the 0.665PZ0.46T0.54-0.335PZNN ceramic, which has a rhombohedral structure, exhibited a large g33 value of 43 × 10-3 Vm/N and a d33 × g33 value of 27 000 × 10-15m2/N. Therefore, this ceramic is a good candidate for multilayer actuators and piezoelectric energy harvesters.

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