Structural combination of polar hollow microspheres and hierarchical N-doped carbon nanotubes for high-performance Li-S batteries

Jun Yeob Lee, Gi Dae Park, Jae Hun Choi, Yun Chan Kang

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20 Citations (Scopus)


Hierarchical structured materials constructed with conductive carbon materials have been extensively studied as S host materials for Li-S batteries. However, their outwardly developed hierarchical structures, which do not contain structures or materials to inhibit polysulfide dissolution, lead to the dissipation of dissolved polysulfides and poor dispersion properties during the slurry-making process, which results in non-uniformity in the cathodes. Herein, an assembly of polar materials (hollow structured SiO2 microspheres) and electrically conductive hierarchical N-doped bamboo-like carbon nanotubes (b-NCNTs) is designed as an efficient S host material for minimizing the dissolution of polysulfides during Li-S battery operations. Highly aligned and packed b-NCNTs are grown in hollow structured SiO2 microspheres. The SiO2 layer coated on the surface of the hollow CoFe2O4 microspheres plays a key role in the synthesis of easily dispersible hierarchical b-NCNTs microspheres (b-NCNTs@SiO2). The S-loaded b-NCNTs@SiO2 electrodes show better cycling stability than S-loaded b-NCNTs electrodes. The polysulfide trapping of the polar SiO2 layer and the well-developed b-NCNTs minimize the dissolution of polysulfides during cycling. In addition, the introduction of electronegative N atoms into the b-NCNTs lattice enhances their polysulfide trapping ability. The S-loaded b-NCNTs@SiO2 electrodes exhibit stable discharge capacities of >771 mA h g-1 over 195 cycles at a current density of 0.5 C and a high reversible capacity of 486 mA h g-1 even at a high current density of 5.0 C.

Original languageEnglish
Pages (from-to)2142-2153
Number of pages12
Issue number3
Publication statusPublished - 2020 Jan 21

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2017R1A2B2008592 and NRF-2017R1A4A1014806).

Publisher Copyright:
© 2020 The Royal Society of Chemistry.

ASJC Scopus subject areas

  • General Materials Science


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