Structural variation and microwave dielectric properties of TiO2- doped Ba(Zn1/3Ta2/3)O3 ceramics

Min Han Kim, Sahn Nahm, Woo Sung Lee, Myong Jae Yoo, Nam Gi Gang, Hwack Joo Lee

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    15 Citations (Scopus)

    Abstract

    The effect of TiO2 on microstructure and microwave dielectric properties of Ba(Zn1/3Ta2/3 O3 (BZT) ceramics was investigated. The addition of TiO2 did not disturb the 1:2 ordering structure of the BZT ceramic. The average grain size significantly increased with the addition of TiO2, which was attributed to the liquid phase formation. A small amount of TiO2 increased the relative density. However, relative density decreased with the addition of the large amount of TiO2 and it might be due to the abnormal grain growth. The Q value of the BZT significantly improved with the addition of the TiO2 for the specimens sintered at 1580 °C and it could be explained by the increased relative density. However, for the specimens sintered at 1630 °C, Q value decreased with the addition of the TiO2 which is attributed to the decrease of the relative density. The maximum Q×f value achieved in this investigation was about 135,000 GHz for the BZT with 1.0 mol.% TiO2 sintered at 1580 °C for 10 h.

    Original languageEnglish
    Pages (from-to)3547-3552
    Number of pages6
    JournalJournal of the European Ceramic Society
    Volume24
    Issue number13
    DOIs
    Publication statusPublished - 2004 Oct

    Bibliographical note

    Funding Information:
    This work was supported by the Ministry of Science and Technology through the project of Nano-Technology and one of the authors also acknowledges that this work was financially supported by the Ministry of Science and Technology through the NRL Project.

    Keywords

    • Ba(Zn, Ta )O
    • Dielectric properties
    • Microstructure
    • TiO

    ASJC Scopus subject areas

    • Ceramics and Composites
    • Materials Chemistry

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