Studies of the diastereoselective alkylation of enolate dianion of (S)-4-carboethoxymethyl-2-oxazolidinone

Deok Chan Ha, Kun Eek Kil, Kwang Sun Choi, Hye Sang Park

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    16 Citations (Scopus)

    Abstract

    Diastereoselective alkylation of enolate dianion of (S)-4-carboethyoxymethyl-2-oxazolidinone has been studied. The increased anti-selectivity in the presence of HMPA was explained by stereoelectronic effect of the electron-rich nitrogen atom of the oxazolidinone amidate.

    Original languageEnglish
    Pages (from-to)5723-5726
    Number of pages4
    JournalTetrahedron Letters
    Volume37
    Issue number32
    DOIs
    Publication statusPublished - 1996 Aug 5

    Bibliographical note

    Funding Information:
    Acknowledgment. Financial support from Korea Science and Engineering Foundation, and Ministry of Education through Basic Research Institute Program is gratefully acknowledged.

    ASJC Scopus subject areas

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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