Sulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactor

Yong Su Jo; Mansurbek Abdullaev; Gwang Hwa Jin; Bhabani Sankar Swain; Byongpil Lee; Hyung Sub Eom; Seok Hong Min; Seok Ki Kim; Young Keun Kim; Seung Min Yang

doi:10.1021/acsomega.2c05281

Sulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactor

Yong Su Jo, Mansurbek Abdullaev, Gwang Hwa Jin, Bhabani Sankar Swain, Byongpil Lee, Hyung Sub Eom, Seok Hong Min, Seok Ki Kim, Young Keun Kim, Seung Min Yang

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In this study, we investigated the effect of the sulfur content in the NiCl2 precursor on the shape of nickel nanoparticles (Ni-NPs) prepared by chemical vapor synthesis. We obtained spherical Ni-NPs when using anhydrous NiCl2 mixed with NiSO4 or Na2SO4 with a molar ratio of 0.002 as precursors without changing any other process parameters whereas faceted Ni-NPs when using only anhydrous NiCl2 as a precursor. First-principles calculations supported experimental results, which showed that NiSO4-mixed NiCl2 and Na2SO4-mixed NiCl2 precursors favored the growth of spherical NPs.

Original language	English
Pages (from-to)	43958-43964
Number of pages	7
Journal	ACS Omega
Volume	7
Issue number	48
DOIs	https://doi.org/10.1021/acsomega.2c05281
Publication status	Published - 2022 Dec 6

Bibliographical note

Publisher Copyright:
© 2022 The Authors. Published by American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1021/acsomega.2c05281

Cite this

@article{b7e91af25a9e4d86ac6af68f2b6d2a01,

title = "Sulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactor",

abstract = "In this study, we investigated the effect of the sulfur content in the NiCl2 precursor on the shape of nickel nanoparticles (Ni-NPs) prepared by chemical vapor synthesis. We obtained spherical Ni-NPs when using anhydrous NiCl2 mixed with NiSO4 or Na2SO4 with a molar ratio of 0.002 as precursors without changing any other process parameters whereas faceted Ni-NPs when using only anhydrous NiCl2 as a precursor. First-principles calculations supported experimental results, which showed that NiSO4-mixed NiCl2 and Na2SO4-mixed NiCl2 precursors favored the growth of spherical NPs.",

author = "Jo, {Yong Su} and Mansurbek Abdullaev and Jin, {Gwang Hwa} and Swain, {Bhabani Sankar} and Byongpil Lee and Eom, {Hyung Sub} and Min, {Seok Hong} and Kim, {Seok Ki} and Kim, {Young Keun} and Yang, {Seung Min}",

note = "Publisher Copyright: {\textcopyright} 2022 The Authors. Published by American Chemical Society.",

year = "2022",

month = dec,

day = "6",

doi = "10.1021/acsomega.2c05281",

language = "English",

volume = "7",

pages = "43958--43964",

journal = "ACS Omega",

issn = "2470-1343",

publisher = "American Chemical Society",

number = "48",

}

TY - JOUR

T1 - Sulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactor

AU - Jo, Yong Su

AU - Abdullaev, Mansurbek

AU - Jin, Gwang Hwa

AU - Swain, Bhabani Sankar

AU - Lee, Byongpil

AU - Eom, Hyung Sub

AU - Min, Seok Hong

AU - Kim, Seok Ki

AU - Kim, Young Keun

AU - Yang, Seung Min

PY - 2022/12/6

Y1 - 2022/12/6

N2 - In this study, we investigated the effect of the sulfur content in the NiCl2 precursor on the shape of nickel nanoparticles (Ni-NPs) prepared by chemical vapor synthesis. We obtained spherical Ni-NPs when using anhydrous NiCl2 mixed with NiSO4 or Na2SO4 with a molar ratio of 0.002 as precursors without changing any other process parameters whereas faceted Ni-NPs when using only anhydrous NiCl2 as a precursor. First-principles calculations supported experimental results, which showed that NiSO4-mixed NiCl2 and Na2SO4-mixed NiCl2 precursors favored the growth of spherical NPs.

AB - In this study, we investigated the effect of the sulfur content in the NiCl2 precursor on the shape of nickel nanoparticles (Ni-NPs) prepared by chemical vapor synthesis. We obtained spherical Ni-NPs when using anhydrous NiCl2 mixed with NiSO4 or Na2SO4 with a molar ratio of 0.002 as precursors without changing any other process parameters whereas faceted Ni-NPs when using only anhydrous NiCl2 as a precursor. First-principles calculations supported experimental results, which showed that NiSO4-mixed NiCl2 and Na2SO4-mixed NiCl2 precursors favored the growth of spherical NPs.

UR - http://www.scopus.com/inward/record.url?scp=85143078702&partnerID=8YFLogxK

U2 - 10.1021/acsomega.2c05281

DO - 10.1021/acsomega.2c05281

M3 - Article

AN - SCOPUS:85143078702

SN - 2470-1343

VL - 7

SP - 43958

EP - 43964

JO - ACS Omega

JF - ACS Omega

IS - 48

ER -

Sulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactor

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this