Sum-frequency vibrational spectroscopic study of surface glass transition of poly(vinyl alcohol)

Chun Zhang; Seok Cheol Hong; Na Ji; Yen Po Wang; Kung Hwa Wei; Y. R. Shen

doi:10.1021/ma025681s

Sum-frequency vibrational spectroscopic study of surface glass transition of poly(vinyl alcohol)

Chun Zhang, Seok Cheol Hong, Na Ji, Yen Po Wang, Kung Hwa Wei, Y. R. Shen

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Sum-frequency vibrational spectroscopy was employed to study surface glass transition of poly(vinyl alcohol) by monitoring the relaxation of rubbing-induced alignment of surface chains with increase of temperature. The observed chain relaxation is two-dimensional, parallel to the surface. The surface transition temperature is 58 ± 2 °C, essentially the same as the bulk one.

Original language	English
Pages (from-to)	3303-3306
Number of pages	4
Journal	Macromolecules
Volume	36
Issue number	9
DOIs	https://doi.org/10.1021/ma025681s
Publication status	Published - 2003 May 6
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1021/ma025681s

Cite this

@article{a7960739ec2a4503a6fd0091abe4a3ff,

title = "Sum-frequency vibrational spectroscopic study of surface glass transition of poly(vinyl alcohol)",

abstract = "Sum-frequency vibrational spectroscopy was employed to study surface glass transition of poly(vinyl alcohol) by monitoring the relaxation of rubbing-induced alignment of surface chains with increase of temperature. The observed chain relaxation is two-dimensional, parallel to the surface. The surface transition temperature is 58 ± 2 °C, essentially the same as the bulk one.",

author = "Chun Zhang and Hong, {Seok Cheol} and Na Ji and Wang, {Yen Po} and Wei, {Kung Hwa} and Shen, {Y. R.}",

year = "2003",

month = may,

day = "6",

doi = "10.1021/ma025681s",

language = "English",

volume = "36",

pages = "3303--3306",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Sum-frequency vibrational spectroscopic study of surface glass transition of poly(vinyl alcohol)

AU - Zhang, Chun

AU - Hong, Seok Cheol

AU - Ji, Na

AU - Wang, Yen Po

AU - Wei, Kung Hwa

AU - Shen, Y. R.

PY - 2003/5/6

Y1 - 2003/5/6

N2 - Sum-frequency vibrational spectroscopy was employed to study surface glass transition of poly(vinyl alcohol) by monitoring the relaxation of rubbing-induced alignment of surface chains with increase of temperature. The observed chain relaxation is two-dimensional, parallel to the surface. The surface transition temperature is 58 ± 2 °C, essentially the same as the bulk one.

AB - Sum-frequency vibrational spectroscopy was employed to study surface glass transition of poly(vinyl alcohol) by monitoring the relaxation of rubbing-induced alignment of surface chains with increase of temperature. The observed chain relaxation is two-dimensional, parallel to the surface. The surface transition temperature is 58 ± 2 °C, essentially the same as the bulk one.

UR - http://www.scopus.com/inward/record.url?scp=0038779611&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038779611&partnerID=8YFLogxK

U2 - 10.1021/ma025681s

DO - 10.1021/ma025681s

M3 - Article

AN - SCOPUS:0038779611

SN - 0024-9297

VL - 36

SP - 3303

EP - 3306

JO - Macromolecules

JF - Macromolecules

IS - 9

ER -

Sum-frequency vibrational spectroscopic study of surface glass transition of poly(vinyl alcohol)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this