Supersonically sprayed gas- and water-sensing MIL-100(Fe) films

Jong Gun Lee; Bhavana N. Joshi; Edmund Samuel; Seongpil An; Mark T. Swihart; Ji Sun Lee; Young Kyu Hwang; Jong San Chang; Sam S. Yoon

doi:10.1016/j.jallcom.2017.06.190

Supersonically sprayed gas- and water-sensing MIL-100(Fe) films

Jong Gun Lee, Bhavana N. Joshi, Edmund Samuel, Seongpil An, Mark T. Swihart, Ji Sun Lee, Young Kyu Hwang, Jong San Chang, Sam S. Yoon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Highly uniform, mechanically stable, dense, and water-adsorbing MIL-100(Fe) films were fabricated via supersonic spraying, a rapid, high-throughput, and scalable method compatible with roll-to-roll processing. The film surface area (1667 m² g⁻¹) was comparable to that of the nanoparticles from which it was prepared (2009 m² g⁻¹), and was higher than previously reported values for MIL-100(Fe) films. The gas and water adsorption abilities of the film were tested by nitrogen physisorption and water adsorption at 30 °C. The supersonically sprayed film was mechanically resistant up to a critical scratching load of 1.84 N, higher than the critical scratchability loads of dip-coated or spin-coated films. In humidity-sensing applications, films that incorporated conductive Ag nanowires were highly responsive to environmental humidity, demonstrating applicability as water vapor sensors. The fabricated films were characterized by X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, and atomic force microscopy.

Original language	English
Pages (from-to)	996-1001
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	722
DOIs	https://doi.org/10.1016/j.jallcom.2017.06.190
Publication status	Published - 2017 Oct 25

Bibliographical note

Publisher Copyright:
© 2017 Elsevier B.V.

Keywords

Humidity sensor
MIL-100
Supersonic spraying
Water adsorption

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/j.jallcom.2017.06.190

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title = "Supersonically sprayed gas- and water-sensing MIL-100(Fe) films",

abstract = "Highly uniform, mechanically stable, dense, and water-adsorbing MIL-100(Fe) films were fabricated via supersonic spraying, a rapid, high-throughput, and scalable method compatible with roll-to-roll processing. The film surface area (1667 m2 g−1) was comparable to that of the nanoparticles from which it was prepared (2009 m2 g−1), and was higher than previously reported values for MIL-100(Fe) films. The gas and water adsorption abilities of the film were tested by nitrogen physisorption and water adsorption at 30 °C. The supersonically sprayed film was mechanically resistant up to a critical scratching load of 1.84 N, higher than the critical scratchability loads of dip-coated or spin-coated films. In humidity-sensing applications, films that incorporated conductive Ag nanowires were highly responsive to environmental humidity, demonstrating applicability as water vapor sensors. The fabricated films were characterized by X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, and atomic force microscopy.",

keywords = "Humidity sensor, MIL-100, Supersonic spraying, Water adsorption",

author = "Lee, \{Jong Gun\} and Joshi, \{Bhavana N.\} and Edmund Samuel and Seongpil An and Swihart, \{Mark T.\} and Lee, \{Ji Sun\} and Hwang, \{Young Kyu\} and Chang, \{Jong San\} and Yoon, \{Sam S.\}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = oct,

day = "25",

doi = "10.1016/j.jallcom.2017.06.190",

language = "English",

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T1 - Supersonically sprayed gas- and water-sensing MIL-100(Fe) films

AU - Lee, Jong Gun

AU - Joshi, Bhavana N.

AU - Samuel, Edmund

AU - An, Seongpil

AU - Swihart, Mark T.

AU - Lee, Ji Sun

AU - Hwang, Young Kyu

AU - Chang, Jong San

AU - Yoon, Sam S.

PY - 2017/10/25

Y1 - 2017/10/25

N2 - Highly uniform, mechanically stable, dense, and water-adsorbing MIL-100(Fe) films were fabricated via supersonic spraying, a rapid, high-throughput, and scalable method compatible with roll-to-roll processing. The film surface area (1667 m2 g−1) was comparable to that of the nanoparticles from which it was prepared (2009 m2 g−1), and was higher than previously reported values for MIL-100(Fe) films. The gas and water adsorption abilities of the film were tested by nitrogen physisorption and water adsorption at 30 °C. The supersonically sprayed film was mechanically resistant up to a critical scratching load of 1.84 N, higher than the critical scratchability loads of dip-coated or spin-coated films. In humidity-sensing applications, films that incorporated conductive Ag nanowires were highly responsive to environmental humidity, demonstrating applicability as water vapor sensors. The fabricated films were characterized by X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, and atomic force microscopy.

AB - Highly uniform, mechanically stable, dense, and water-adsorbing MIL-100(Fe) films were fabricated via supersonic spraying, a rapid, high-throughput, and scalable method compatible with roll-to-roll processing. The film surface area (1667 m2 g−1) was comparable to that of the nanoparticles from which it was prepared (2009 m2 g−1), and was higher than previously reported values for MIL-100(Fe) films. The gas and water adsorption abilities of the film were tested by nitrogen physisorption and water adsorption at 30 °C. The supersonically sprayed film was mechanically resistant up to a critical scratching load of 1.84 N, higher than the critical scratchability loads of dip-coated or spin-coated films. In humidity-sensing applications, films that incorporated conductive Ag nanowires were highly responsive to environmental humidity, demonstrating applicability as water vapor sensors. The fabricated films were characterized by X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, and atomic force microscopy.

KW - Humidity sensor

KW - MIL-100

KW - Supersonic spraying

KW - Water adsorption

UR - https://www.scopus.com/pages/publications/85021355632

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DO - 10.1016/j.jallcom.2017.06.190

M3 - Article

AN - SCOPUS:85021355632

SN - 0925-8388

VL - 722

SP - 996

EP - 1001

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Supersonically sprayed gas- and water-sensing MIL-100(Fe) films

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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