Surface mechanical properties of poly(urethane acrylate)/silica hybrid interpenetrating polymer network (IPN) coatings

Min Seop Um; Dong Seok Ham; Seong Keun Cho; Sang Jin Lee; Kwang Je Kim; Jae Heung Lee; Sung Hoon Choa; Hyun Wook Jung; Woo Jin Choi

doi:10.1016/j.porgcoat.2016.04.007

Surface mechanical properties of poly(urethane acrylate)/silica hybrid interpenetrating polymer network (IPN) coatings

Min Seop Um, Dong Seok Ham, Seong Keun Cho, Sang Jin Lee, Kwang Je Kim, Jae Heung Lee, Sung Hoon Choa, Hyun Wook Jung, Woo Jin Choi

Department of Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Surface mechanical properties of poly(urethane acrylate) (PUA)/silica hybrid interpenetrating polymer network (IPN) coating materials were investigated using several test methods including nano-indentation, nano-scratch, pencil hardness, and stretching. To prepare coated films, an organic part (urethane acrylate) was mixed with an inorganic part (silica) at various ratios. Independent crosslinking reactions were applied to form the hybrid IPN structure: UV curing and sol-gel reactions were used for the organic and inorganic parts, respectively. The prepared hybrid IPN coatings exhibited no macroscopic phase separation. As the silica content was increased, the values for indentation hardness and pencil hardness increased, while failure strain during stretching test decreased. It was found that the hybrid IPN coating with its balanced dissipative and elastic properties had better scratch resistance than that of other coatings.

Original language	English
Pages (from-to)	166-174
Number of pages	9
Journal	Progress in Organic Coatings
Volume	97
DOIs	https://doi.org/10.1016/j.porgcoat.2016.04.007
Publication status	Published - 2016 Aug

Keywords

Dissipative and elastic energy ratios
Failure strain during stretching test
Hard coating film
Nano-indentation test
Nano-scratch test
Pencil hardness test

ASJC Scopus subject areas

Chemical Engineering(all)
Surfaces, Coatings and Films
Organic Chemistry
Materials Chemistry

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title = "Surface mechanical properties of poly(urethane acrylate)/silica hybrid interpenetrating polymer network (IPN) coatings",

abstract = "Surface mechanical properties of poly(urethane acrylate) (PUA)/silica hybrid interpenetrating polymer network (IPN) coating materials were investigated using several test methods including nano-indentation, nano-scratch, pencil hardness, and stretching. To prepare coated films, an organic part (urethane acrylate) was mixed with an inorganic part (silica) at various ratios. Independent crosslinking reactions were applied to form the hybrid IPN structure: UV curing and sol-gel reactions were used for the organic and inorganic parts, respectively. The prepared hybrid IPN coatings exhibited no macroscopic phase separation. As the silica content was increased, the values for indentation hardness and pencil hardness increased, while failure strain during stretching test decreased. It was found that the hybrid IPN coating with its balanced dissipative and elastic properties had better scratch resistance than that of other coatings.",

keywords = "Dissipative and elastic energy ratios, Failure strain during stretching test, Hard coating film, Nano-indentation test, Nano-scratch test, Pencil hardness test",

author = "Um, {Min Seop} and Ham, {Dong Seok} and Cho, {Seong Keun} and Lee, {Sang Jin} and Kim, {Kwang Je} and Lee, {Jae Heung} and Choa, {Sung Hoon} and Jung, {Hyun Wook} and Choi, {Woo Jin}",

note = "Funding Information: This research was supported by a grant from the Korea Research Institute of Chemical Technology (KRICT) (Project No.: KK1506-C00, Development of Functional Coating Technology).. Publisher Copyright: {\textcopyright} 2016 Elsevier B.V. All rights reserved.",

year = "2016",

month = aug,

doi = "10.1016/j.porgcoat.2016.04.007",

language = "English",

volume = "97",

pages = "166--174",

journal = "Progress in Organic Coatings",

issn = "0300-9440",

publisher = "Elsevier",

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AU - Um, Min Seop

AU - Ham, Dong Seok

AU - Cho, Seong Keun

AU - Lee, Sang Jin

AU - Kim, Kwang Je

AU - Lee, Jae Heung

AU - Choa, Sung Hoon

AU - Jung, Hyun Wook

AU - Choi, Woo Jin

N1 - Funding Information: This research was supported by a grant from the Korea Research Institute of Chemical Technology (KRICT) (Project No.: KK1506-C00, Development of Functional Coating Technology).. Publisher Copyright: © 2016 Elsevier B.V. All rights reserved.

PY - 2016/8

Y1 - 2016/8

N2 - Surface mechanical properties of poly(urethane acrylate) (PUA)/silica hybrid interpenetrating polymer network (IPN) coating materials were investigated using several test methods including nano-indentation, nano-scratch, pencil hardness, and stretching. To prepare coated films, an organic part (urethane acrylate) was mixed with an inorganic part (silica) at various ratios. Independent crosslinking reactions were applied to form the hybrid IPN structure: UV curing and sol-gel reactions were used for the organic and inorganic parts, respectively. The prepared hybrid IPN coatings exhibited no macroscopic phase separation. As the silica content was increased, the values for indentation hardness and pencil hardness increased, while failure strain during stretching test decreased. It was found that the hybrid IPN coating with its balanced dissipative and elastic properties had better scratch resistance than that of other coatings.

AB - Surface mechanical properties of poly(urethane acrylate) (PUA)/silica hybrid interpenetrating polymer network (IPN) coating materials were investigated using several test methods including nano-indentation, nano-scratch, pencil hardness, and stretching. To prepare coated films, an organic part (urethane acrylate) was mixed with an inorganic part (silica) at various ratios. Independent crosslinking reactions were applied to form the hybrid IPN structure: UV curing and sol-gel reactions were used for the organic and inorganic parts, respectively. The prepared hybrid IPN coatings exhibited no macroscopic phase separation. As the silica content was increased, the values for indentation hardness and pencil hardness increased, while failure strain during stretching test decreased. It was found that the hybrid IPN coating with its balanced dissipative and elastic properties had better scratch resistance than that of other coatings.

KW - Dissipative and elastic energy ratios

KW - Failure strain during stretching test

KW - Hard coating film

KW - Nano-indentation test

KW - Nano-scratch test

KW - Pencil hardness test

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ER -

Surface mechanical properties of poly(urethane acrylate)/silica hybrid interpenetrating polymer network (IPN) coatings

Abstract

Keywords

ASJC Scopus subject areas

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