Surface-modified Nafion membrane by oleylamine-stabilized Pd nanoparticles for DMFC applications

Ai Hua Tian, Ji Young Kim, Jin Yi Shi, Keon Kim, Kwangyeol Lee

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)


The surface of Nafion was modified by applying palladium nanoparticles as methanol barrier materials to decrease methanol crossover and improve the performance of fuel cells. The properties of the Pd-modified membrane, in terms of conductivity, methanol permeability, percentage of liquid uptake as well as the performance of its membrane electrode assembly (MEA) in the direct methanol fuel cell, were analyzed and compared with those using bare Nafion. The modified membrane showed considerable improvement on reducing methanol loss without decreasing proton conductivity. The DMFC performance of modified membrane was superior to that of bare Nafion both at a typical fuel state of 2 M and at high concentration of 5 M, implying that the palladium-modified Nafion can be a good alternative approach for DMFC applications.

Original languageEnglish
Pages (from-to)302-308
Number of pages7
JournalJournal of Power Sources
Issue number2
Publication statusPublished - 2007 May 15

Bibliographical note

Funding Information:
This work was supported by the core technology development program for fuel cell of Ministry of Science and Technology and Korea Institute of Science and Technology Evaluation and Planning, as well as the Korea Research Foundation Grant funded by the Korea Government (MOEHRD). (KRF-2005-211-C00069).


  • Direct methanol fuel cell
  • Methanol crossover
  • Modified Nafion
  • Palladium

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering


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