Synergistic MXene/LDH heterostructures with extensive interfacing as emerging energy conversion and storage materials

Sandhya Venkateshalu, Gracita M. Tomboc, Suruthi Priya Nagalingam, Jun Kim, Tehzeeb Sawaira, Kashaf Sehar, Bruno G. Pollet, Jin Young Kim, Andrews Nirmala Grace, Kwangyeol Lee

Research output: Contribution to journalReview articlepeer-review

6 Citations (Scopus)

Abstract

The heterostructures of different two-dimensional (2D) materials have garnered significant attention recently as emerging energy conversion and storage systems. Combining highly conductive and surface-active 2D MXenes with multifunctional 2D layered double hydroxides (LDHs) can leverage the constructive properties of both 2D materials. The synergistic interactions at the interface of MXene/LDH heterostructures enable them to exhibit commendable electrochemical performance and alleviate the disadvantages of the individual components. By comprehending the interfacial interactions between these two 2D materials, the structural, electronic, and morphological properties of the hybrid can be optimized. To this end, in addition to the discussions of the established synthetic methods for MXene/LDH hybrids, this article critically reviews their growth mechanism and factors influencing the morphology and chemical properties of the composites. Furthermore, the electronic interactions at the MXene/LDH heterointerface and their role in enhancing the electrochemical properties favorable to energy applications are systematically discussed. Finally, the key challenges and prospective research guidelines are provided to encourage further research to explore the synergistic effects of 2D/2D MXene/LDH hybrids in building better energy conversion and storage systems.

Original languageEnglish
Pages (from-to)14469-14488
Number of pages20
JournalJournal of Materials Chemistry A
Volume11
Issue number27
DOIs
Publication statusPublished - 2023 Jun 2

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea, Grant No. NRF-2020K1A3A1A19088726, NRF-2019R1A6A1A11044070, and NRF-2021M3H4A1A02049916. This work was also supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government (MOTIE) (Grant No. 20203020030010 and 20213030030260), and the program of Future Hydrogen Original Technology Development (NRF-2021M3I3A1082879) through the National Research Foundation of Korea (NRF) funded by the Korean government (Ministry of Science and ICT). G. M. Tomboc thanks NSERC CRC in Green Hydrogen Production for their support.

Publisher Copyright:
© 2023 The Royal Society of Chemistry.

ASJC Scopus subject areas

  • General Chemistry
  • Renewable Energy, Sustainability and the Environment
  • General Materials Science

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