Synthesis and Electrochemical Properties of HT-LiCo0.8Ni0.2O2 Prepared by Molten Salt Synthesis Method using 0.59LiNO3-0.41LiOH System

Chi Hwan Han; Young Sik Hong; Eun Ju Kang; Jee Sun Shin; Keon Kim

doi:10.1007/BF02706398

Synthesis and Electrochemical Properties of HT-LiCo_0.8Ni_0.2O₂ Prepared by Molten Salt Synthesis Method using 0.59LiNO₃-0.41LiOH System

Chi Hwan Han
, Young Sik Hong
, Eun Ju Kang
, Jee Sun Shin
, Keon Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

LiCo_0.8Ni_0.2O₂ powders were prepared by molten salt synthesis method using a 0.59LiNO₃-0.41LiOH melt. The physico-chemical properties of the LiCo_0.8Ni_0.2O₂ powders were investigated by powder X-ray diffraction method, field emission scanning electron microscopy, cyclic voltammetry, and charge-discharge cycling. Uniform size nanocrystalline powder (∼40 nm) could be obtained at temperature ranges of 280-480°C. These nanocrystalline powders showed poor electrochemical properties because of presence of the low temperature phase. Pure single-phase HT-LiCo_0.8Ni_0.2O₂ powder could be obtained at 580°C. Charge-discharge measurements indicated that this exhibited a good capacity and cyclability without further heat treatment at higher temperatures.

Original language	English
Pages (from-to)	765-769
Number of pages	5
Journal	Korean Journal of Chemical Engineering
Volume	18
Issue number	5
DOIs	https://doi.org/10.1007/BF02706398
Publication status	Published - 2001 Sept

Keywords

LiCoNiO
Lithium Battery
Molten Salt Synthesis

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1007/BF02706398

Cite this

@article{6f0968ce06be4730bdcab47818af7e1a,

title = "Synthesis and Electrochemical Properties of HT-LiCo0.8Ni0.2O2 Prepared by Molten Salt Synthesis Method using 0.59LiNO3-0.41LiOH System",

abstract = "LiCo0.8Ni0.2O2 powders were prepared by molten salt synthesis method using a 0.59LiNO3-0.41LiOH melt. The physico-chemical properties of the LiCo0.8Ni0.2O2 powders were investigated by powder X-ray diffraction method, field emission scanning electron microscopy, cyclic voltammetry, and charge-discharge cycling. Uniform size nanocrystalline powder (∼40 nm) could be obtained at temperature ranges of 280-480°C. These nanocrystalline powders showed poor electrochemical properties because of presence of the low temperature phase. Pure single-phase HT-LiCo0.8Ni0.2O2 powder could be obtained at 580°C. Charge-discharge measurements indicated that this exhibited a good capacity and cyclability without further heat treatment at higher temperatures.",

keywords = "LiCoNiO, Lithium Battery, Molten Salt Synthesis",

author = "Han, \{Chi Hwan\} and Hong, \{Young Sik\} and Kang, \{Eun Ju\} and Shin, \{Jee Sun\} and Keon Kim",

year = "2001",

month = sep,

doi = "10.1007/BF02706398",

language = "English",

volume = "18",

pages = "765--769",

journal = "Korean Journal of Chemical Engineering",

issn = "0256-1115",

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TY - JOUR

T1 - Synthesis and Electrochemical Properties of HT-LiCo0.8Ni0.2O2 Prepared by Molten Salt Synthesis Method using 0.59LiNO3-0.41LiOH System

AU - Han, Chi Hwan

AU - Hong, Young Sik

AU - Kang, Eun Ju

AU - Shin, Jee Sun

AU - Kim, Keon

PY - 2001/9

Y1 - 2001/9

N2 - LiCo0.8Ni0.2O2 powders were prepared by molten salt synthesis method using a 0.59LiNO3-0.41LiOH melt. The physico-chemical properties of the LiCo0.8Ni0.2O2 powders were investigated by powder X-ray diffraction method, field emission scanning electron microscopy, cyclic voltammetry, and charge-discharge cycling. Uniform size nanocrystalline powder (∼40 nm) could be obtained at temperature ranges of 280-480°C. These nanocrystalline powders showed poor electrochemical properties because of presence of the low temperature phase. Pure single-phase HT-LiCo0.8Ni0.2O2 powder could be obtained at 580°C. Charge-discharge measurements indicated that this exhibited a good capacity and cyclability without further heat treatment at higher temperatures.

AB - LiCo0.8Ni0.2O2 powders were prepared by molten salt synthesis method using a 0.59LiNO3-0.41LiOH melt. The physico-chemical properties of the LiCo0.8Ni0.2O2 powders were investigated by powder X-ray diffraction method, field emission scanning electron microscopy, cyclic voltammetry, and charge-discharge cycling. Uniform size nanocrystalline powder (∼40 nm) could be obtained at temperature ranges of 280-480°C. These nanocrystalline powders showed poor electrochemical properties because of presence of the low temperature phase. Pure single-phase HT-LiCo0.8Ni0.2O2 powder could be obtained at 580°C. Charge-discharge measurements indicated that this exhibited a good capacity and cyclability without further heat treatment at higher temperatures.

KW - LiCoNiO

KW - Lithium Battery

KW - Molten Salt Synthesis

UR - https://www.scopus.com/pages/publications/0035623605

U2 - 10.1007/BF02706398

DO - 10.1007/BF02706398

M3 - Article

AN - SCOPUS:0035623605

SN - 0256-1115

VL - 18

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EP - 769

JO - Korean Journal of Chemical Engineering

JF - Korean Journal of Chemical Engineering

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