Synthesis and nonlinear optical properties of 1,3,5-tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives

Bong Rae Cho; Young Hoon Kim; Kyung Wha Son; Chajara Khalil; Yong Ho Kim; Seung Joon Jeon

doi:10.5012/bkcs.2002.23.9.1253

Synthesis and nonlinear optical properties of 1,3,5-tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives

Bong Rae Cho, Young Hoon Kim, Kyung Wha Son, Chajara Khalil, Yong Ho Kim, Seung Joon Jeon

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl] benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λ_max values increased with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the β value increased with conjugation length. In contrast, the b values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.

Original language	English
Pages (from-to)	1253-1256
Number of pages	4
Journal	Bulletin of the Korean Chemical Society
Volume	23
Issue number	9
DOIs	https://doi.org/10.5012/bkcs.2002.23.9.1253
Publication status	Published - 2002 Sept 20

Keywords

Nonlinear optics
Octupole
Thiophene

ASJC Scopus subject areas

General Chemistry

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10.5012/bkcs.2002.23.9.1253

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abstract = "1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl] benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λmax values increased with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the β value increased with conjugation length. In contrast, the b values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.",

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T1 - Synthesis and nonlinear optical properties of 1,3,5-tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives

AU - Cho, Bong Rae

AU - Kim, Young Hoon

AU - Son, Kyung Wha

AU - Khalil, Chajara

AU - Kim, Yong Ho

AU - Jeon, Seung Joon

PY - 2002/9/20

Y1 - 2002/9/20

N2 - 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl] benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λmax values increased with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the β value increased with conjugation length. In contrast, the b values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.

AB - 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl] benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λmax values increased with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the β value increased with conjugation length. In contrast, the b values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.

KW - Nonlinear optics

KW - Octupole

KW - Thiophene

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SN - 0253-2964

VL - 23

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JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

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ER -

Synthesis and nonlinear optical properties of 1,3,5-tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives

Abstract

Keywords

ASJC Scopus subject areas

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