Utilizing a planar five coordinating N3S2 ligand, 2,6-bis(2-methylthiophenyliminomethyl)pyridine, a pseudo 7-coordinated manganese(II) complex with two labile triflate anions in the axial positions was synthesized. The reaction of the manganese(I oI) complex with an oxidant, iodosylbenzene, produced a metastable high-valent manganese(IV)-oxo species at 0 °C. The high-valent Mn(IV)-oxo intermediate was characterized with a UV-vis spectrophotometer and an electrospray ionization mass spectroscopy. Reactivity studies of the Mn(IV)=O species revealed that the intermediate is capable of oxygenating PPh3 and N-dealkylating N, N-dimethyl-toludine.
|Number of pages||4|
|Journal||Bulletin of the Korean Chemical Society|
|Publication status||Published - 2009 Mar|
- Bioinorganic chemistry
- High-valent manganese-oxo
- Seven coordination
ASJC Scopus subject areas