Synthesis and separating properties of tris(Merrifield peptide resin)

Won Kim Dong; Suk Kim Chang; Nam Soo Lee; Haiil Ryu; Seung Kim Jong; Hun Jang Young

doi:10.1515/znb-2002-0113

Synthesis and separating properties of tris(Merrifield peptide resin)

Won Kim Dong, Suk Kim Chang, Nam Soo Lee, Haiil Ryu, Seung Kim Jong, Hun Jang Young

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A triazacrown ion exchanger, 1,13,16-trioxa-4,7,10-triazacyclooctadecane (TOTA)-4,7,10-tris(Merrifield peptide resin) was synthesized. This resin has a capacity of 0.1 meq/g dry resin. The resin was used for the elution chromatographic separation of lithium isotopes. Upon column chromatography [0.2 cm I. D. × 35 cm height] using 3.0 M NH₄Cl solution as an eluent, the single stage separation factor of 1.027 was obtained. The heavier isotope, ⁷Li⁺, was enriched in the resin phase, while the lighter isotope, ⁶Li⁺, was enriched in the solution phase.

Original language	English
Pages (from-to)	107-112
Number of pages	6
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	57
Issue number	1
DOIs	https://doi.org/10.1515/znb-2002-0113
Publication status	Published - 2002
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported by the Basic Science Research Institute Program, Ministry of Education, Republic of Korea, 1998, Project No. BSRI-98Ð3435.

Keywords

Elution Chromatography
Isotope Separation
Triazacrown

ASJC Scopus subject areas

General Chemistry

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10.1515/znb-2002-0113

Cite this

@article{48ca3c2465b745f8b6e8758b63a3203e,

title = "Synthesis and separating properties of tris(Merrifield peptide resin)",

abstract = "A triazacrown ion exchanger, 1,13,16-trioxa-4,7,10-triazacyclooctadecane (TOTA)-4,7,10-tris(Merrifield peptide resin) was synthesized. This resin has a capacity of 0.1 meq/g dry resin. The resin was used for the elution chromatographic separation of lithium isotopes. Upon column chromatography [0.2 cm I. D. × 35 cm height] using 3.0 M NH4Cl solution as an eluent, the single stage separation factor of 1.027 was obtained. The heavier isotope, 7Li+, was enriched in the resin phase, while the lighter isotope, 6Li+, was enriched in the solution phase.",

keywords = "Elution Chromatography, Isotope Separation, Triazacrown",

author = "Dong, {Won Kim} and Chang, {Suk Kim} and Lee, {Nam Soo} and Haiil Ryu and Jong, {Seung Kim} and Young, {Hun Jang}",

note = "Funding Information: This work was supported by the Basic Science Research Institute Program, Ministry of Education, Republic of Korea, 1998, Project No. BSRI-98{\DH}3435.",

year = "2002",

doi = "10.1515/znb-2002-0113",

language = "English",

volume = "57",

pages = "107--112",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

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TY - JOUR

T1 - Synthesis and separating properties of tris(Merrifield peptide resin)

AU - Dong, Won Kim

AU - Chang, Suk Kim

AU - Lee, Nam Soo

AU - Ryu, Haiil

AU - Jong, Seung Kim

AU - Young, Hun Jang

N1 - Funding Information: This work was supported by the Basic Science Research Institute Program, Ministry of Education, Republic of Korea, 1998, Project No. BSRI-98Ð3435.

PY - 2002

Y1 - 2002

N2 - A triazacrown ion exchanger, 1,13,16-trioxa-4,7,10-triazacyclooctadecane (TOTA)-4,7,10-tris(Merrifield peptide resin) was synthesized. This resin has a capacity of 0.1 meq/g dry resin. The resin was used for the elution chromatographic separation of lithium isotopes. Upon column chromatography [0.2 cm I. D. × 35 cm height] using 3.0 M NH4Cl solution as an eluent, the single stage separation factor of 1.027 was obtained. The heavier isotope, 7Li+, was enriched in the resin phase, while the lighter isotope, 6Li+, was enriched in the solution phase.

AB - A triazacrown ion exchanger, 1,13,16-trioxa-4,7,10-triazacyclooctadecane (TOTA)-4,7,10-tris(Merrifield peptide resin) was synthesized. This resin has a capacity of 0.1 meq/g dry resin. The resin was used for the elution chromatographic separation of lithium isotopes. Upon column chromatography [0.2 cm I. D. × 35 cm height] using 3.0 M NH4Cl solution as an eluent, the single stage separation factor of 1.027 was obtained. The heavier isotope, 7Li+, was enriched in the resin phase, while the lighter isotope, 6Li+, was enriched in the solution phase.

KW - Elution Chromatography

KW - Isotope Separation

KW - Triazacrown

UR - http://www.scopus.com/inward/record.url?scp=0036345810&partnerID=8YFLogxK

U2 - 10.1515/znb-2002-0113

DO - 10.1515/znb-2002-0113

M3 - Article

AN - SCOPUS:0036345810

SN - 0932-0776

VL - 57

SP - 107

EP - 112

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 1

ER -

Synthesis and separating properties of tris(Merrifield peptide resin)

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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