Synthesis of acyclic polyethers bearing thioamide end-groups and selective sensing of silver ion

Jong Seung Kim; Ill Yong Yu; Jin Hyun Pang; Moon Hwan Cho; Jae Hoon Cho; Dong Won Kim; Jae Hyung Yoo; Seon Gil Kwon

doi:10.1023/A:1008063902389

Synthesis of acyclic polyethers bearing thioamide end-groups and selective sensing of silver ion

Jong Seung Kim, Ill Yong Yu, Jin Hyun Pang, Moon Hwan Cho, Jae Hoon Cho, Dong Won Kim, Jae Hyung Yoo, Seon Gil Kwon

Research output: Contribution to journal › Article › peer-review

Abstract

A series of acyclic polyethers bearing thioamide end-groups and lipophilic alkyl chains were successfully synthesized with moderate yields. Transport measurements in a bulk liquid membrane (BLM) system indicated a very high selectivity of silver ion over other metal cations. Thermodynamic parameters (ΔH, TΔS, and log K) for ligand-metal ion complexations were determined by solution calorimetric titration in methanol at 25 °C. The complexations were enthalpy driven and silver ion exhibited a high selectivity over other metal ions due to the increase of covalent binding between the soft acid (Ag⁺) and soft base (sulfur).

Original language	English
Pages (from-to)	321-330
Number of pages	10
Journal	Journal of Inclusion Phenomena
Volume	34
Issue number	3
DOIs	https://doi.org/10.1023/A:1008063902389
Publication status	Published - 1999 Jul
Externally published	Yes

Keywords

Complexation
Ion selectivity
Polyether
Thermodynamic parameter
Thioamides
Transport

ASJC Scopus subject areas

Food Science
Chemistry(all)
Condensed Matter Physics

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10.1023/A:1008063902389

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@article{23c34e84882748649d9df43ae03b18ff,

title = "Synthesis of acyclic polyethers bearing thioamide end-groups and selective sensing of silver ion",

abstract = "A series of acyclic polyethers bearing thioamide end-groups and lipophilic alkyl chains were successfully synthesized with moderate yields. Transport measurements in a bulk liquid membrane (BLM) system indicated a very high selectivity of silver ion over other metal cations. Thermodynamic parameters (ΔH, TΔS, and log K) for ligand-metal ion complexations were determined by solution calorimetric titration in methanol at 25 °C. The complexations were enthalpy driven and silver ion exhibited a high selectivity over other metal ions due to the increase of covalent binding between the soft acid (Ag+) and soft base (sulfur).",

keywords = "Complexation, Ion selectivity, Polyether, Thermodynamic parameter, Thioamides, Transport",

author = "Kim, {Jong Seung} and Yu, {Ill Yong} and Pang, {Jin Hyun} and Cho, {Moon Hwan} and Cho, {Jae Hoon} and Kim, {Dong Won} and Yoo, {Jae Hyung} and Kwon, {Seon Gil}",

note = "Funding Information: This study was supported by the Academic Research fund of the Ministry of Education, Republic of Korea (BSRI-96-3440). Also, we gratefully thank the Korea Atomic Energy Research Institute for their financial support.",

year = "1999",

month = jul,

doi = "10.1023/A:1008063902389",

language = "English",

volume = "34",

pages = "321--330",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

issn = "1388-3127",

publisher = "Kluwer Academic Publishers",

number = "3",

}

TY - JOUR

T1 - Synthesis of acyclic polyethers bearing thioamide end-groups and selective sensing of silver ion

AU - Kim, Jong Seung

AU - Yu, Ill Yong

AU - Pang, Jin Hyun

AU - Cho, Moon Hwan

AU - Cho, Jae Hoon

AU - Kim, Dong Won

AU - Yoo, Jae Hyung

AU - Kwon, Seon Gil

N1 - Funding Information: This study was supported by the Academic Research fund of the Ministry of Education, Republic of Korea (BSRI-96-3440). Also, we gratefully thank the Korea Atomic Energy Research Institute for their financial support.

PY - 1999/7

Y1 - 1999/7

N2 - A series of acyclic polyethers bearing thioamide end-groups and lipophilic alkyl chains were successfully synthesized with moderate yields. Transport measurements in a bulk liquid membrane (BLM) system indicated a very high selectivity of silver ion over other metal cations. Thermodynamic parameters (ΔH, TΔS, and log K) for ligand-metal ion complexations were determined by solution calorimetric titration in methanol at 25 °C. The complexations were enthalpy driven and silver ion exhibited a high selectivity over other metal ions due to the increase of covalent binding between the soft acid (Ag+) and soft base (sulfur).

AB - A series of acyclic polyethers bearing thioamide end-groups and lipophilic alkyl chains were successfully synthesized with moderate yields. Transport measurements in a bulk liquid membrane (BLM) system indicated a very high selectivity of silver ion over other metal cations. Thermodynamic parameters (ΔH, TΔS, and log K) for ligand-metal ion complexations were determined by solution calorimetric titration in methanol at 25 °C. The complexations were enthalpy driven and silver ion exhibited a high selectivity over other metal ions due to the increase of covalent binding between the soft acid (Ag+) and soft base (sulfur).

KW - Complexation

KW - Ion selectivity

KW - Polyether

KW - Thermodynamic parameter

KW - Thioamides

KW - Transport

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U2 - 10.1023/A:1008063902389

DO - 10.1023/A:1008063902389

M3 - Article

AN - SCOPUS:0033164858

SN - 1388-3127

VL - 34

SP - 321

EP - 330

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 3

ER -

Synthesis of acyclic polyethers bearing thioamide end-groups and selective sensing of silver ion

Abstract

Keywords

ASJC Scopus subject areas

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