Synthesis of Cu-Pd nanoplates and their catalytic performance for H2O2 generation reaction

Zengmin Tang; Geun Ho Han; Euiyoung Jung; Myung gi Seo; Kwan Young Lee; Woo Sik Kim; Taekyung Yu

doi:10.1016/j.mcat.2018.04.010

Synthesis of Cu-Pd nanoplates and their catalytic performance for H₂O₂ generation reaction

Zengmin Tang
, Geun Ho Han
, Euiyoung Jung
, Myung gi Seo
, Kwan Young Lee
, Woo Sik Kim^*
, Taekyung Yu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

We reported on an aqueous-phase synthesis of copper-palladium (Cu-Pd) nanoplates consisting of 5 nm-sized Pd nanoparticles deposited on Cu nanoplates. In the present synthesis, ascorbic acid was used as a reducing agent to prevent galvanic replacement. By controlling the experimental conditions, we could control the weight percent of Pd in the nanoplates from 0.56% to 2.02%. The Cu-Pd nanoplates with Pd content of 2.02% exhibited high catalytic performance in the direct H₂O₂ generation reaction.

Original language	English
Pages (from-to)	117-122
Number of pages	6
Journal	Molecular Catalysis
Volume	452
DOIs	https://doi.org/10.1016/j.mcat.2018.04.010
Publication status	Published - 2018 Jun

Bibliographical note

Funding Information:
This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2014R1A5A1009799, NRF-2015R1C1A1A01054109, NRF-2017R1E1A2A02081585, and NRF-2016M3D1A1021140).

Keywords

Aqueous-phase synthesis
Ascorbic acid
Cu-Pd nanoplates
HO generation reaction

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

Access to Document

10.1016/j.mcat.2018.04.010

Cite this

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title = "Synthesis of Cu-Pd nanoplates and their catalytic performance for H2O2 generation reaction",

abstract = "We reported on an aqueous-phase synthesis of copper-palladium (Cu-Pd) nanoplates consisting of 5 nm-sized Pd nanoparticles deposited on Cu nanoplates. In the present synthesis, ascorbic acid was used as a reducing agent to prevent galvanic replacement. By controlling the experimental conditions, we could control the weight percent of Pd in the nanoplates from 0.56\% to 2.02\%. The Cu-Pd nanoplates with Pd content of 2.02\% exhibited high catalytic performance in the direct H2O2 generation reaction.",

keywords = "Aqueous-phase synthesis, Ascorbic acid, Cu-Pd nanoplates, HO generation reaction",

author = "Zengmin Tang and Han, \{Geun Ho\} and Euiyoung Jung and Seo, \{Myung gi\} and Lee, \{Kwan Young\} and Kim, \{Woo Sik\} and Taekyung Yu",

note = "Funding Information: This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2014R1A5A1009799, NRF-2015R1C1A1A01054109, NRF-2017R1E1A2A02081585, and NRF-2016M3D1A1021140). ",

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doi = "10.1016/j.mcat.2018.04.010",

language = "English",

volume = "452",

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AU - Tang, Zengmin

AU - Han, Geun Ho

AU - Jung, Euiyoung

AU - Seo, Myung gi

AU - Lee, Kwan Young

AU - Kim, Woo Sik

AU - Yu, Taekyung

N1 - Funding Information: This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2014R1A5A1009799, NRF-2015R1C1A1A01054109, NRF-2017R1E1A2A02081585, and NRF-2016M3D1A1021140).

PY - 2018/6

Y1 - 2018/6

N2 - We reported on an aqueous-phase synthesis of copper-palladium (Cu-Pd) nanoplates consisting of 5 nm-sized Pd nanoparticles deposited on Cu nanoplates. In the present synthesis, ascorbic acid was used as a reducing agent to prevent galvanic replacement. By controlling the experimental conditions, we could control the weight percent of Pd in the nanoplates from 0.56% to 2.02%. The Cu-Pd nanoplates with Pd content of 2.02% exhibited high catalytic performance in the direct H2O2 generation reaction.

AB - We reported on an aqueous-phase synthesis of copper-palladium (Cu-Pd) nanoplates consisting of 5 nm-sized Pd nanoparticles deposited on Cu nanoplates. In the present synthesis, ascorbic acid was used as a reducing agent to prevent galvanic replacement. By controlling the experimental conditions, we could control the weight percent of Pd in the nanoplates from 0.56% to 2.02%. The Cu-Pd nanoplates with Pd content of 2.02% exhibited high catalytic performance in the direct H2O2 generation reaction.

KW - Aqueous-phase synthesis

KW - Ascorbic acid

KW - Cu-Pd nanoplates

KW - HO generation reaction

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