Synthesis of Cu3(MoO4)2(OH)2 nanostructures by simple aqueous precipitation: understanding the fundamental chemistry and growth mechanism

Basudev Swain; Duk Hee Lee; Jae Ryang Park; Chan Gi Lee; Kun Jae Lee; Dong Wan Kim; Kyung Soo Park

doi:10.1039/c6ce02344d

Synthesis of Cu₃(MoO₄)₂(OH)₂ nanostructures by simple aqueous precipitation: understanding the fundamental chemistry and growth mechanism

Basudev Swain, Duk Hee Lee, Jae Ryang Park, Chan Gi Lee, Kun Jae Lee, Dong Wan Kim, Kyung Soo Park

School of Civil, Environmental and Architectural Engineering

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Lindgrenite (Cu₃(MoO₄)₂(OH)₂) nanoflowers were synthesized through the simplest possible route by an aqueous chemical precipitation technique at room temperature without using any surfactants, template, expensive chemicals, complex instrumentation or tedious multistage synthesis process. Their morphology, structure, thermal properties, surface area, synthesis chemistry, and structural and growth mechanisms involved in the synthesis process were analyzed. Using XRD, FE-SEM, HR-TEM and FT-IR spectroscopy, their structure and morphology were analyzed. The thermal stability, surface area and porosity of the Cu₃(MoO₄)₂(OH)₂ nanoflowers were analyzed by TGA and BET. XRD analysis showed that the Cu₃(MoO₄)₂(OH)₂ nanoflowers have a pure monoclinic structure. The morphological analysis showed that the Cu₃(MoO₄)₂(OH)₂ nanoflowers are ∼10 μm in size, which are formed from self-assembly of thin nanosheets with a thickness of ∼20 nm. TGA indicated that the Cu₃(MoO₄)₂(OH)₂ nanoflowers are stable materials up to 328 °C and the isotherm from BET analysis indicated that the Cu₃(MoO₄)₂(OH)₂ nanoflowers are non-porous materials. The BET surface area of the synthesized Cu₃(MoO₄)₂(OH)₂ nanoflowers was found to be 21.357 m² g^-1. Moreover, the effects of the pH value and reaction time on the morphology of the Cu₃(MoO₄)₂(OH)₂ nanoflowers were studied and their optimization was performed. The results of the optimization study indicated that the reaction time and pH are two important parameters influencing the nucleation, growth, morphology, and synthesis mechanism. These flower-shaped Cu₃(MoO₄)₂(OH)₂ nanostructures are promising precursors for preparing molybdenum oxide materials which have various applications and can be synthesized in a very simple one-pot reaction system using commonly available chemicals without using a complex route.

Original language	English
Pages (from-to)	154-165
Number of pages	12
Journal	CrystEngComm
Volume	19
Issue number	1
DOIs	https://doi.org/10.1039/c6ce02344d
Publication status	Published - 2017

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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@article{095c10a43072460984b717d5a70b0a6a,

title = "Synthesis of Cu3(MoO4)2(OH)2 nanostructures by simple aqueous precipitation: understanding the fundamental chemistry and growth mechanism",

abstract = "Lindgrenite (Cu3(MoO4)2(OH)2) nanoflowers were synthesized through the simplest possible route by an aqueous chemical precipitation technique at room temperature without using any surfactants, template, expensive chemicals, complex instrumentation or tedious multistage synthesis process. Their morphology, structure, thermal properties, surface area, synthesis chemistry, and structural and growth mechanisms involved in the synthesis process were analyzed. Using XRD, FE-SEM, HR-TEM and FT-IR spectroscopy, their structure and morphology were analyzed. The thermal stability, surface area and porosity of the Cu3(MoO4)2(OH)2 nanoflowers were analyzed by TGA and BET. XRD analysis showed that the Cu3(MoO4)2(OH)2 nanoflowers have a pure monoclinic structure. The morphological analysis showed that the Cu3(MoO4)2(OH)2 nanoflowers are ∼10 μm in size, which are formed from self-assembly of thin nanosheets with a thickness of ∼20 nm. TGA indicated that the Cu3(MoO4)2(OH)2 nanoflowers are stable materials up to 328 °C and the isotherm from BET analysis indicated that the Cu3(MoO4)2(OH)2 nanoflowers are non-porous materials. The BET surface area of the synthesized Cu3(MoO4)2(OH)2 nanoflowers was found to be 21.357 m2 g-1. Moreover, the effects of the pH value and reaction time on the morphology of the Cu3(MoO4)2(OH)2 nanoflowers were studied and their optimization was performed. The results of the optimization study indicated that the reaction time and pH are two important parameters influencing the nucleation, growth, morphology, and synthesis mechanism. These flower-shaped Cu3(MoO4)2(OH)2 nanostructures are promising precursors for preparing molybdenum oxide materials which have various applications and can be synthesized in a very simple one-pot reaction system using commonly available chemicals without using a complex route.",

author = "Basudev Swain and Lee, {Duk Hee} and Park, {Jae Ryang} and Lee, {Chan Gi} and Lee, {Kun Jae} and Kim, {Dong Wan} and Park, {Kyung Soo}",

note = "Funding Information: This study was supported by the Korea Ministry of the Environment under 'Global-top program'(2016002250005). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6ce02344d",

language = "English",

volume = "19",

pages = "154--165",

journal = "CrystEngComm",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis of Cu3(MoO4)2(OH)2 nanostructures by simple aqueous precipitation

T2 - understanding the fundamental chemistry and growth mechanism

AU - Swain, Basudev

AU - Lee, Duk Hee

AU - Park, Jae Ryang

AU - Lee, Chan Gi

AU - Lee, Kun Jae

AU - Kim, Dong Wan

AU - Park, Kyung Soo

N1 - Funding Information: This study was supported by the Korea Ministry of the Environment under 'Global-top program'(2016002250005). Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - Lindgrenite (Cu3(MoO4)2(OH)2) nanoflowers were synthesized through the simplest possible route by an aqueous chemical precipitation technique at room temperature without using any surfactants, template, expensive chemicals, complex instrumentation or tedious multistage synthesis process. Their morphology, structure, thermal properties, surface area, synthesis chemistry, and structural and growth mechanisms involved in the synthesis process were analyzed. Using XRD, FE-SEM, HR-TEM and FT-IR spectroscopy, their structure and morphology were analyzed. The thermal stability, surface area and porosity of the Cu3(MoO4)2(OH)2 nanoflowers were analyzed by TGA and BET. XRD analysis showed that the Cu3(MoO4)2(OH)2 nanoflowers have a pure monoclinic structure. The morphological analysis showed that the Cu3(MoO4)2(OH)2 nanoflowers are ∼10 μm in size, which are formed from self-assembly of thin nanosheets with a thickness of ∼20 nm. TGA indicated that the Cu3(MoO4)2(OH)2 nanoflowers are stable materials up to 328 °C and the isotherm from BET analysis indicated that the Cu3(MoO4)2(OH)2 nanoflowers are non-porous materials. The BET surface area of the synthesized Cu3(MoO4)2(OH)2 nanoflowers was found to be 21.357 m2 g-1. Moreover, the effects of the pH value and reaction time on the morphology of the Cu3(MoO4)2(OH)2 nanoflowers were studied and their optimization was performed. The results of the optimization study indicated that the reaction time and pH are two important parameters influencing the nucleation, growth, morphology, and synthesis mechanism. These flower-shaped Cu3(MoO4)2(OH)2 nanostructures are promising precursors for preparing molybdenum oxide materials which have various applications and can be synthesized in a very simple one-pot reaction system using commonly available chemicals without using a complex route.

AB - Lindgrenite (Cu3(MoO4)2(OH)2) nanoflowers were synthesized through the simplest possible route by an aqueous chemical precipitation technique at room temperature without using any surfactants, template, expensive chemicals, complex instrumentation or tedious multistage synthesis process. Their morphology, structure, thermal properties, surface area, synthesis chemistry, and structural and growth mechanisms involved in the synthesis process were analyzed. Using XRD, FE-SEM, HR-TEM and FT-IR spectroscopy, their structure and morphology were analyzed. The thermal stability, surface area and porosity of the Cu3(MoO4)2(OH)2 nanoflowers were analyzed by TGA and BET. XRD analysis showed that the Cu3(MoO4)2(OH)2 nanoflowers have a pure monoclinic structure. The morphological analysis showed that the Cu3(MoO4)2(OH)2 nanoflowers are ∼10 μm in size, which are formed from self-assembly of thin nanosheets with a thickness of ∼20 nm. TGA indicated that the Cu3(MoO4)2(OH)2 nanoflowers are stable materials up to 328 °C and the isotherm from BET analysis indicated that the Cu3(MoO4)2(OH)2 nanoflowers are non-porous materials. The BET surface area of the synthesized Cu3(MoO4)2(OH)2 nanoflowers was found to be 21.357 m2 g-1. Moreover, the effects of the pH value and reaction time on the morphology of the Cu3(MoO4)2(OH)2 nanoflowers were studied and their optimization was performed. The results of the optimization study indicated that the reaction time and pH are two important parameters influencing the nucleation, growth, morphology, and synthesis mechanism. These flower-shaped Cu3(MoO4)2(OH)2 nanostructures are promising precursors for preparing molybdenum oxide materials which have various applications and can be synthesized in a very simple one-pot reaction system using commonly available chemicals without using a complex route.

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Synthesis of Cu₃(MoO₄)₂(OH)₂ nanostructures by simple aqueous precipitation: understanding the fundamental chemistry and growth mechanism

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