Synthesis of photocurable fluorenylidene diacrylate for optical application

Mina Jeon; Bong Rea Cho; Mijeong Han; Changjin Lee; Sung Cheol Yoon

doi:10.1080/15421400802330762

Synthesis of photocurable fluorenylidene diacrylate for optical application

Mina Jeon, Bong Rea Cho, Mijeong Han, Changjin Lee, Sung Cheol Yoon

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We reported on synthesis and characterization of fluorenylidene diacrylate, which has high refractive index and low optical loss for optical application. Polymer film was easily prepared by spin-coating a solution of monomer with photoinitiator (Irgacure 369) and cured under 365 nm UV light illumination. This film has a good chemical/mechanical resistance as well as a high thermal stability. The refractive index of this film at 830 nm was obtained as 1.5948 and 1.5947 for TE and TM polarization, respectively. Also, this film shows extremely low birefringence of 0.0001 and very low propagation loss of 0.08 dB/cm at 830 nm for TE polarization. It was demonstrated that these newly synthesized fluorenylidene diacrylate was promising candidate for optical waveguide materials.

Original language	English
Pages (from-to)	303/[667]-311/[675]
Journal	Molecular Crystals and Liquid Crystals
Volume	492
DOIs	https://doi.org/10.1080/15421400802330762
Publication status	Published - 2008

Bibliographical note

Funding Information:
This work was supported by Ministry of Commerce, Industry, and Energy (MOCIE) for materials and components technology development program in South Korea.

Keywords

High refractive index
Low birefringence
Low propagation loss
Optical waveguide
Photocurable

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1080/15421400802330762

Cite this

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title = "Synthesis of photocurable fluorenylidene diacrylate for optical application",

abstract = "We reported on synthesis and characterization of fluorenylidene diacrylate, which has high refractive index and low optical loss for optical application. Polymer film was easily prepared by spin-coating a solution of monomer with photoinitiator (Irgacure 369) and cured under 365 nm UV light illumination. This film has a good chemical/mechanical resistance as well as a high thermal stability. The refractive index of this film at 830 nm was obtained as 1.5948 and 1.5947 for TE and TM polarization, respectively. Also, this film shows extremely low birefringence of 0.0001 and very low propagation loss of 0.08 dB/cm at 830 nm for TE polarization. It was demonstrated that these newly synthesized fluorenylidene diacrylate was promising candidate for optical waveguide materials.",

keywords = "High refractive index, Low birefringence, Low propagation loss, Optical waveguide, Photocurable",

author = "Mina Jeon and Cho, {Bong Rea} and Mijeong Han and Changjin Lee and Yoon, {Sung Cheol}",

note = "Funding Information: This work was supported by Ministry of Commerce, Industry, and Energy (MOCIE) for materials and components technology development program in South Korea.",

year = "2008",

doi = "10.1080/15421400802330762",

language = "English",

volume = "492",

pages = "303/[667]--311/[675]",

journal = "Molecular Crystals and Liquid Crystals",

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publisher = "Taylor and Francis Ltd.",

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T1 - Synthesis of photocurable fluorenylidene diacrylate for optical application

AU - Jeon, Mina

AU - Cho, Bong Rea

AU - Han, Mijeong

AU - Lee, Changjin

AU - Yoon, Sung Cheol

N1 - Funding Information: This work was supported by Ministry of Commerce, Industry, and Energy (MOCIE) for materials and components technology development program in South Korea.

PY - 2008

Y1 - 2008

N2 - We reported on synthesis and characterization of fluorenylidene diacrylate, which has high refractive index and low optical loss for optical application. Polymer film was easily prepared by spin-coating a solution of monomer with photoinitiator (Irgacure 369) and cured under 365 nm UV light illumination. This film has a good chemical/mechanical resistance as well as a high thermal stability. The refractive index of this film at 830 nm was obtained as 1.5948 and 1.5947 for TE and TM polarization, respectively. Also, this film shows extremely low birefringence of 0.0001 and very low propagation loss of 0.08 dB/cm at 830 nm for TE polarization. It was demonstrated that these newly synthesized fluorenylidene diacrylate was promising candidate for optical waveguide materials.

AB - We reported on synthesis and characterization of fluorenylidene diacrylate, which has high refractive index and low optical loss for optical application. Polymer film was easily prepared by spin-coating a solution of monomer with photoinitiator (Irgacure 369) and cured under 365 nm UV light illumination. This film has a good chemical/mechanical resistance as well as a high thermal stability. The refractive index of this film at 830 nm was obtained as 1.5948 and 1.5947 for TE and TM polarization, respectively. Also, this film shows extremely low birefringence of 0.0001 and very low propagation loss of 0.08 dB/cm at 830 nm for TE polarization. It was demonstrated that these newly synthesized fluorenylidene diacrylate was promising candidate for optical waveguide materials.

KW - High refractive index

KW - Low birefringence

KW - Low propagation loss

KW - Optical waveguide

KW - Photocurable

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DO - 10.1080/15421400802330762

M3 - Article

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SN - 1542-1406

VL - 492

SP - 303/[667]-311/[675]

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

Synthesis of photocurable fluorenylidene diacrylate for optical application

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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