Synthesis of Second-Order Nonlinear Optical Polymers Containing Stilbazoljum Salt Chromophore in the Side Chain

Dong Hoon Choi; Sangyup Song; Sun Jin Lim; Soo Young Park; Nakjoong Kim

doi:10.1080/10587259508033972

Synthesis of Second-Order Nonlinear Optical Polymers Containing Stilbazoljum Salt Chromophore in the Side Chain

Dong Hoon Choi, Sangyup Song, Sun Jin Lim, Soo Young Park, Nakjoong Kim

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We synthesized novel side chain copolymers containing the stilbazolium tetraphenylborate for the linear electro-optic coefficient measurement These polymers are very soluble in common organic solvents such as acetone, cyclohexanone, dimethylformamide etc. The second-order nonlinear optical properties of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenylborate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]carbamate-co-methylmethacrylate] (POLYMER la & lb), poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate] -N- [(1,1 -dimethyl - m -isopropenyl)bezyl]carbamate-co-N-vinylcarbazole] (POLYMERII), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1 -dimethyl-m-isopropenyl)benzyl]carbamate-co-4-hydroxyphenyl maleimide] (POLYMER III) were improved due to the change of the nonlinear optical chromophore in the side chain.

Original language	English
Pages (from-to)	53-58
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals
Volume	267
Issue number	1
DOIs	https://doi.org/10.1080/10587259508033972
Publication status	Published - 1995 Oct 1
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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title = "Synthesis of Second-Order Nonlinear Optical Polymers Containing Stilbazoljum Salt Chromophore in the Side Chain",

abstract = "We synthesized novel side chain copolymers containing the stilbazolium tetraphenylborate for the linear electro-optic coefficient measurement These polymers are very soluble in common organic solvents such as acetone, cyclohexanone, dimethylformamide etc. The second-order nonlinear optical properties of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenylborate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]carbamate-co-methylmethacrylate] (POLYMER la & lb), poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate] -N- [(1,1 -dimethyl - m -isopropenyl)bezyl]carbamate-co-N-vinylcarbazole] (POLYMERII), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1 -dimethyl-m-isopropenyl)benzyl]carbamate-co-4-hydroxyphenyl maleimide] (POLYMER III) were improved due to the change of the nonlinear optical chromophore in the side chain.",

author = "Choi, {Dong Hoon} and Sangyup Song and Lim, {Sun Jin} and Park, {Soo Young} and Nakjoong Kim",

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AU - Choi, Dong Hoon

AU - Song, Sangyup

AU - Lim, Sun Jin

AU - Park, Soo Young

AU - Kim, Nakjoong

PY - 1995/10/1

Y1 - 1995/10/1

N2 - We synthesized novel side chain copolymers containing the stilbazolium tetraphenylborate for the linear electro-optic coefficient measurement These polymers are very soluble in common organic solvents such as acetone, cyclohexanone, dimethylformamide etc. The second-order nonlinear optical properties of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenylborate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]carbamate-co-methylmethacrylate] (POLYMER la & lb), poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate] -N- [(1,1 -dimethyl - m -isopropenyl)bezyl]carbamate-co-N-vinylcarbazole] (POLYMERII), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1 -dimethyl-m-isopropenyl)benzyl]carbamate-co-4-hydroxyphenyl maleimide] (POLYMER III) were improved due to the change of the nonlinear optical chromophore in the side chain.

AB - We synthesized novel side chain copolymers containing the stilbazolium tetraphenylborate for the linear electro-optic coefficient measurement These polymers are very soluble in common organic solvents such as acetone, cyclohexanone, dimethylformamide etc. The second-order nonlinear optical properties of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenylborate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]carbamate-co-methylmethacrylate] (POLYMER la & lb), poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate] -N- [(1,1 -dimethyl - m -isopropenyl)bezyl]carbamate-co-N-vinylcarbazole] (POLYMERII), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1 -dimethyl-m-isopropenyl)benzyl]carbamate-co-4-hydroxyphenyl maleimide] (POLYMER III) were improved due to the change of the nonlinear optical chromophore in the side chain.

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Synthesis of Second-Order Nonlinear Optical Polymers Containing Stilbazoljum Salt Chromophore in the Side Chain

Abstract

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