Synthesis, X-ray crystal structure, and electrochemistry of trans-bis(ferrocenecarboxylato)(tetraphenylporphyrinato)tin(IV)

Hee Jung Kim; Woo Sung Jeon; Jeong Hak Lim; Chang Seop Hong; Hee Joon Kim

doi:10.1016/j.poly.2006.12.023

Synthesis, X-ray crystal structure, and electrochemistry of trans-bis(ferrocenecarboxylato)(tetraphenylporphyrinato)tin(IV)

Hee Jung Kim, Woo Sung Jeon, Jeong Hak Lim, Chang Seop Hong, Hee Joon Kim

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

trans-Bis(ferrocenecarboxylato)(5,10,15,20-tetraphenylporphyrinato)tin(IV) complex Sn(TPP)(FcCOO)₂ has been synthesized and fully characterized. The X-ray structural analysis of Sn(TPP)(FcCOO)₂ reveals that the tin(IV) center is octahedrally coordinated by the porphyrin occupying the square base and axial coordination of two ferrocenecarboxylato ligands in an anti orientation with respect to each other. The Fe(II) center of the ferrocenecarboxylato ligand lies 5.7 Å from the tin(IV) center of the porphyrin ring. The cyclic voltammogram of Sn(TPP)(FcCOO)₂ exhibits three distinctive redox couples consisting of one oxidative wave and two reductive waves due to the ferrocenecarboxylato ligands and the porphyrin ring, respectively.

Original language	English
Pages (from-to)	2517-2522
Number of pages	6
Journal	Polyhedron
Volume	26
Issue number	12
DOIs	https://doi.org/10.1016/j.poly.2006.12.023
Publication status	Published - 2007 Jul 23

Bibliographical note

Funding Information:
This work was supported by Kumoh National Institute of Technology. We thank Mr. Ilha Hwang for preliminary measurements of cyclic voltammetry.

Keywords

Cyclic voltammogram
Ferrocenecarboxylato ligands
Porphyrin
Tin(IV) complex
X-ray crystal structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2006.12.023

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title = "Synthesis, X-ray crystal structure, and electrochemistry of trans-bis(ferrocenecarboxylato)(tetraphenylporphyrinato)tin(IV)",

abstract = "trans-Bis(ferrocenecarboxylato)(5,10,15,20-tetraphenylporphyrinato)tin(IV) complex Sn(TPP)(FcCOO)2 has been synthesized and fully characterized. The X-ray structural analysis of Sn(TPP)(FcCOO)2 reveals that the tin(IV) center is octahedrally coordinated by the porphyrin occupying the square base and axial coordination of two ferrocenecarboxylato ligands in an anti orientation with respect to each other. The Fe(II) center of the ferrocenecarboxylato ligand lies 5.7 {\AA} from the tin(IV) center of the porphyrin ring. The cyclic voltammogram of Sn(TPP)(FcCOO)2 exhibits three distinctive redox couples consisting of one oxidative wave and two reductive waves due to the ferrocenecarboxylato ligands and the porphyrin ring, respectively.",

keywords = "Cyclic voltammogram, Ferrocenecarboxylato ligands, Porphyrin, Tin(IV) complex, X-ray crystal structure",

author = "Kim, {Hee Jung} and Jeon, {Woo Sung} and Lim, {Jeong Hak} and Hong, {Chang Seop} and Kim, {Hee Joon}",

note = "Funding Information: This work was supported by Kumoh National Institute of Technology. We thank Mr. Ilha Hwang for preliminary measurements of cyclic voltammetry. ",

year = "2007",

month = jul,

day = "23",

doi = "10.1016/j.poly.2006.12.023",

language = "English",

volume = "26",

pages = "2517--2522",

journal = "Polyhedron",

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AU - Kim, Hee Jung

AU - Jeon, Woo Sung

AU - Lim, Jeong Hak

AU - Hong, Chang Seop

AU - Kim, Hee Joon

N1 - Funding Information: This work was supported by Kumoh National Institute of Technology. We thank Mr. Ilha Hwang for preliminary measurements of cyclic voltammetry.

PY - 2007/7/23

Y1 - 2007/7/23

N2 - trans-Bis(ferrocenecarboxylato)(5,10,15,20-tetraphenylporphyrinato)tin(IV) complex Sn(TPP)(FcCOO)2 has been synthesized and fully characterized. The X-ray structural analysis of Sn(TPP)(FcCOO)2 reveals that the tin(IV) center is octahedrally coordinated by the porphyrin occupying the square base and axial coordination of two ferrocenecarboxylato ligands in an anti orientation with respect to each other. The Fe(II) center of the ferrocenecarboxylato ligand lies 5.7 Å from the tin(IV) center of the porphyrin ring. The cyclic voltammogram of Sn(TPP)(FcCOO)2 exhibits three distinctive redox couples consisting of one oxidative wave and two reductive waves due to the ferrocenecarboxylato ligands and the porphyrin ring, respectively.

AB - trans-Bis(ferrocenecarboxylato)(5,10,15,20-tetraphenylporphyrinato)tin(IV) complex Sn(TPP)(FcCOO)2 has been synthesized and fully characterized. The X-ray structural analysis of Sn(TPP)(FcCOO)2 reveals that the tin(IV) center is octahedrally coordinated by the porphyrin occupying the square base and axial coordination of two ferrocenecarboxylato ligands in an anti orientation with respect to each other. The Fe(II) center of the ferrocenecarboxylato ligand lies 5.7 Å from the tin(IV) center of the porphyrin ring. The cyclic voltammogram of Sn(TPP)(FcCOO)2 exhibits three distinctive redox couples consisting of one oxidative wave and two reductive waves due to the ferrocenecarboxylato ligands and the porphyrin ring, respectively.

KW - Cyclic voltammogram

KW - Ferrocenecarboxylato ligands

KW - Porphyrin

KW - Tin(IV) complex

KW - X-ray crystal structure

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DO - 10.1016/j.poly.2006.12.023

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JF - Polyhedron

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ER -

Synthesis, X-ray crystal structure, and electrochemistry of trans-bis(ferrocenecarboxylato)(tetraphenylporphyrinato)tin(IV)

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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