Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane

Sung Kwan Kim; Tae Jin Kim; Tae Young Kim; Gaehang Lee; Joon T. Park; Suk Woo Nam; Sang Ook Kang

doi:10.1039/c2cc15931g

Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane

Sung Kwan Kim
, Tae Jin Kim
, Tae Young Kim
, Gaehang Lee
, Joon T. Park
, Suk Woo Nam
, Sang Ook Kang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140 °C, TG promoted Pd₃(OAc)₆ to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia borane (AB) at 85 °C, remarkably enhanced catalytic performance was achieved to release 2.3 equiv. of H₂ in 1 h.

Original language	English
Pages (from-to)	2021-2023
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	14
DOIs	https://doi.org/10.1039/c2cc15931g
Publication status	Published - 2012 Jan 18

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140 °C, TG promoted Pd3(OAc)6 to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia borane (AB) at 85 °C, remarkably enhanced catalytic performance was achieved to release 2.3 equiv. of H2 in 1 h.",

author = "Kim, \{Sung Kwan\} and Kim, \{Tae Jin\} and Kim, \{Tae Young\} and Gaehang Lee and Park, \{Joon T.\} and Nam, \{Suk Woo\} and Kang, \{Sang Ook\}",

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doi = "10.1039/c2cc15931g",

language = "English",

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T1 - Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane

AU - Kim, Sung Kwan

AU - Kim, Tae Jin

AU - Kim, Tae Young

AU - Lee, Gaehang

AU - Park, Joon T.

AU - Nam, Suk Woo

AU - Kang, Sang Ook

PY - 2012/1/18

Y1 - 2012/1/18

N2 - Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140 °C, TG promoted Pd3(OAc)6 to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia borane (AB) at 85 °C, remarkably enhanced catalytic performance was achieved to release 2.3 equiv. of H2 in 1 h.

AB - Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140 °C, TG promoted Pd3(OAc)6 to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia borane (AB) at 85 °C, remarkably enhanced catalytic performance was achieved to release 2.3 equiv. of H2 in 1 h.

UR - https://www.scopus.com/pages/publications/84863062131

U2 - 10.1039/c2cc15931g

DO - 10.1039/c2cc15931g

M3 - Article

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AN - SCOPUS:84863062131

SN - 1359-7345

VL - 48

SP - 2021

EP - 2023

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane

Abstract

ASJC Scopus subject areas

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