The characteristics of Li(CoxNi1 - x)O2 cathode powders formed from the fine-sized Co3O4/NiO precursor powders

Seo Hee Ju; Do Youp Kim; Eun Byul Jo; Yun Chan Kang

doi:10.1016/j.jallcom.2006.11.001

The characteristics of Li(Co_xNi_{1 - x})O₂ cathode powders formed from the fine-sized Co₃O₄/NiO precursor powders

Seo Hee Ju, Do Youp Kim, Eun Byul Jo, Yun Chan Kang

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Li(Co_xNi_{1 - x})O₂ (0 ≤ x ≤ 1) cathode powders were prepared by solid state reaction method using Co₃O₄/NiO precursor powders obtained by spray pyrolysis. The effect of the ratios of cobalt and nickel components on the characteristics of Co₃O₄/NiO precursor and Li(Co_xNi_{1 - x})O₂ cathode powders were investigated. The Co₃O₄/NiO precursor powders with the ratios of cobalt and nickel components as 1/0, 0.75/0.25 and 0.5/0.5 had submicron size and regular morphologies. On the other hand, the Co₃O₄/NiO powders with the high contents of nickel component had aggregated morphologies of submicron size primary powders. The fine-sized precursor powders formed the fine-sized LiCoO₂ and Li(Co_0.75Ni_0.25)O₂ cathode powders by solid state reaction with LiOH powders. However, the high contents of the nickel component of the Co₃O₄/NiO precursor powders formed the Li(Co_xNi_{1 - x})O₂ (0 ≤ x ≤ 0.5) cathode powders with aggregated morphologies and large sizes. The discharge capacities of the powders increased with increasing the nickel content into the Li(Co_xNi_{1 - x})O₂ cathode powders up to 188 mAh/g.

Original language	English
Pages (from-to)	457-462
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	450
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jallcom.2006.11.001
Publication status	Published - 2008 Feb 14
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported by the Division of Advanced Batteries in NGE Program (Project No. = 10016439).

Keywords

Chemical synthesis
Electrode materials
Gas-solid reaction

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/j.jallcom.2006.11.001

Cite this

@article{fc95d6c1ed734ce082d6ba4c783e5d2c,

title = "The characteristics of Li(CoxNi1 - x)O2 cathode powders formed from the fine-sized Co3O4/NiO precursor powders",

abstract = "Li(CoxNi1 - x)O2 (0 ≤ x ≤ 1) cathode powders were prepared by solid state reaction method using Co3O4/NiO precursor powders obtained by spray pyrolysis. The effect of the ratios of cobalt and nickel components on the characteristics of Co3O4/NiO precursor and Li(CoxNi1 - x)O2 cathode powders were investigated. The Co3O4/NiO precursor powders with the ratios of cobalt and nickel components as 1/0, 0.75/0.25 and 0.5/0.5 had submicron size and regular morphologies. On the other hand, the Co3O4/NiO powders with the high contents of nickel component had aggregated morphologies of submicron size primary powders. The fine-sized precursor powders formed the fine-sized LiCoO2 and Li(Co0.75Ni0.25)O2 cathode powders by solid state reaction with LiOH powders. However, the high contents of the nickel component of the Co3O4/NiO precursor powders formed the Li(CoxNi1 - x)O2 (0 ≤ x ≤ 0.5) cathode powders with aggregated morphologies and large sizes. The discharge capacities of the powders increased with increasing the nickel content into the Li(CoxNi1 - x)O2 cathode powders up to 188 mAh/g.",

keywords = "Chemical synthesis, Electrode materials, Gas-solid reaction",

author = "Ju, {Seo Hee} and Kim, {Do Youp} and Jo, {Eun Byul} and Kang, {Yun Chan}",

note = "Funding Information: This work was supported by the Division of Advanced Batteries in NGE Program (Project No. = 10016439).",

year = "2008",

month = feb,

day = "14",

doi = "10.1016/j.jallcom.2006.11.001",

language = "English",

volume = "450",

pages = "457--462",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - The characteristics of Li(CoxNi1 - x)O2 cathode powders formed from the fine-sized Co3O4/NiO precursor powders

AU - Ju, Seo Hee

AU - Kim, Do Youp

AU - Jo, Eun Byul

AU - Kang, Yun Chan

N1 - Funding Information: This work was supported by the Division of Advanced Batteries in NGE Program (Project No. = 10016439).

PY - 2008/2/14

Y1 - 2008/2/14

N2 - Li(CoxNi1 - x)O2 (0 ≤ x ≤ 1) cathode powders were prepared by solid state reaction method using Co3O4/NiO precursor powders obtained by spray pyrolysis. The effect of the ratios of cobalt and nickel components on the characteristics of Co3O4/NiO precursor and Li(CoxNi1 - x)O2 cathode powders were investigated. The Co3O4/NiO precursor powders with the ratios of cobalt and nickel components as 1/0, 0.75/0.25 and 0.5/0.5 had submicron size and regular morphologies. On the other hand, the Co3O4/NiO powders with the high contents of nickel component had aggregated morphologies of submicron size primary powders. The fine-sized precursor powders formed the fine-sized LiCoO2 and Li(Co0.75Ni0.25)O2 cathode powders by solid state reaction with LiOH powders. However, the high contents of the nickel component of the Co3O4/NiO precursor powders formed the Li(CoxNi1 - x)O2 (0 ≤ x ≤ 0.5) cathode powders with aggregated morphologies and large sizes. The discharge capacities of the powders increased with increasing the nickel content into the Li(CoxNi1 - x)O2 cathode powders up to 188 mAh/g.

AB - Li(CoxNi1 - x)O2 (0 ≤ x ≤ 1) cathode powders were prepared by solid state reaction method using Co3O4/NiO precursor powders obtained by spray pyrolysis. The effect of the ratios of cobalt and nickel components on the characteristics of Co3O4/NiO precursor and Li(CoxNi1 - x)O2 cathode powders were investigated. The Co3O4/NiO precursor powders with the ratios of cobalt and nickel components as 1/0, 0.75/0.25 and 0.5/0.5 had submicron size and regular morphologies. On the other hand, the Co3O4/NiO powders with the high contents of nickel component had aggregated morphologies of submicron size primary powders. The fine-sized precursor powders formed the fine-sized LiCoO2 and Li(Co0.75Ni0.25)O2 cathode powders by solid state reaction with LiOH powders. However, the high contents of the nickel component of the Co3O4/NiO precursor powders formed the Li(CoxNi1 - x)O2 (0 ≤ x ≤ 0.5) cathode powders with aggregated morphologies and large sizes. The discharge capacities of the powders increased with increasing the nickel content into the Li(CoxNi1 - x)O2 cathode powders up to 188 mAh/g.

KW - Chemical synthesis

KW - Electrode materials

KW - Gas-solid reaction

UR - http://www.scopus.com/inward/record.url?scp=37349067858&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2006.11.001

DO - 10.1016/j.jallcom.2006.11.001

M3 - Article

AN - SCOPUS:37349067858

SN - 0925-8388

VL - 450

SP - 457

EP - 462

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1-2

ER -