The effect of iron catalysts on the microstructure and tribological properties of carbide-derived carbon

Ji Hoon Jeong, Heung Taek Bae, Dae Soon Lim

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    19 Citations (Scopus)

    Abstract

    Carbide-derived carbon (CDC) films were synthesized on sintered SiC by selective etching at high temperatures. Iron particles were used as a catalyst during the high temperature chlorination process to examine the effect of the catalytic particles on the structure and tribological behavior of CDC films. Chlorination was carried out at temperatures ranging from 1000 to 1200 °C. The structure of the synthesized CDC was characterized and examined by Raman spectroscopy, transmission and scanning electron microscopy. The surface features of the films were analyzed using Auger electron spectroscopy. The results showed that the thickness did not change but the crystallinity was increased by adding the iron catalyst. No significant changes in the coefficient of friction were observed. The wear rate was reduced by adding the catalyst but the decrease was minimized by increasing the processing temperature up to 1150 °C. The observed improvement in the wear resistance was attributed to the increase in hardness as a result of the increase in crystalline phases, such as carbon nanotubes and onion like carbon, due to the presence of the iron catalyst.

    Original languageEnglish
    Pages (from-to)3628-3634
    Number of pages7
    JournalCarbon
    Volume48
    Issue number12
    DOIs
    Publication statusPublished - 2010 Oct

    Bibliographical note

    Funding Information:
    This work was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Commerce, Industry and Energy, Republic of Korea.

    Copyright:
    Copyright 2011 Elsevier B.V., All rights reserved.

    ASJC Scopus subject areas

    • General Chemistry
    • General Materials Science

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