Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry

Young Yeol Jo; Albert S. Lee; Kyung Youl Baek; Heon Lee; Seung Sang Hwang

doi:10.1016/j.polymer.2016.11.040

Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry

Young Yeol Jo, Albert S. Lee, Kyung Youl Baek, Heon Lee, Seung Sang Hwang

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

An in-depth examination of the self-healing properties of both dienophile and diene functionalized ladder-like structured polysilsesquioxane copolymers and terpolymers was investigated. Through functionalization of both diene and dienophile on the double-stranded siloxane backbone with ternary n-alkyl functional groups acting as chain mobility control, the effect of chain mobility and chemical structure on self-healing and mechanical properties were elucidated. All of the single component self-healing hybrid materials exhibited fast healing times (∼5 min), and their de-crosslinked adducts exhibited exceptional retention of solubility in common organic solvents for good reusability, all while having inherent high thermal stability and optical transparency.

Original language	English
Pages (from-to)	58-65
Number of pages	8
Journal	Polymer
Volume	108
DOIs	https://doi.org/10.1016/j.polymer.2016.11.040
Publication status	Published - 2017 Jan 13

Bibliographical note

Funding Information:
This work was financially supported by a grant from the Fundamental R&D Program for Core Technology of Materials, and Industrial Strategic Technology Development Program funded by the Ministry of Knowledge Economy, Republic of Korea . Partial funding was given by the Materials Architecturing Research Center of Korea Institute of Science and Technology (KIST) and the Korea Research Fellowship Program funded by the Ministry of Science , ICT , and Future Planning through the National Research Foundation of Korea .

Publisher Copyright:
© 2016 Elsevier Ltd

Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.

Keywords

Diels-Alder chemistry
Self-healing polymers
Silsesquioxane

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/j.polymer.2016.11.040

Cite this

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title = "Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry",

abstract = "An in-depth examination of the self-healing properties of both dienophile and diene functionalized ladder-like structured polysilsesquioxane copolymers and terpolymers was investigated. Through functionalization of both diene and dienophile on the double-stranded siloxane backbone with ternary n-alkyl functional groups acting as chain mobility control, the effect of chain mobility and chemical structure on self-healing and mechanical properties were elucidated. All of the single component self-healing hybrid materials exhibited fast healing times (∼5 min), and their de-crosslinked adducts exhibited exceptional retention of solubility in common organic solvents for good reusability, all while having inherent high thermal stability and optical transparency.",

keywords = "Diels-Alder chemistry, Self-healing polymers, Silsesquioxane",

author = "Jo, {Young Yeol} and Lee, {Albert S.} and Baek, {Kyung Youl} and Heon Lee and Hwang, {Seung Sang}",

note = "Funding Information: This work was financially supported by a grant from the Fundamental R&D Program for Core Technology of Materials, and Industrial Strategic Technology Development Program funded by the Ministry of Knowledge Economy, Republic of Korea . Partial funding was given by the Materials Architecturing Research Center of Korea Institute of Science and Technology (KIST) and the Korea Research Fellowship Program funded by the Ministry of Science , ICT , and Future Planning through the National Research Foundation of Korea . Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

year = "2017",

month = jan,

day = "13",

doi = "10.1016/j.polymer.2016.11.040",

language = "English",

volume = "108",

pages = "58--65",

journal = "Polymer",

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T1 - Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry

AU - Jo, Young Yeol

AU - Lee, Albert S.

AU - Baek, Kyung Youl

AU - Lee, Heon

AU - Hwang, Seung Sang

N1 - Funding Information: This work was financially supported by a grant from the Fundamental R&D Program for Core Technology of Materials, and Industrial Strategic Technology Development Program funded by the Ministry of Knowledge Economy, Republic of Korea . Partial funding was given by the Materials Architecturing Research Center of Korea Institute of Science and Technology (KIST) and the Korea Research Fellowship Program funded by the Ministry of Science , ICT , and Future Planning through the National Research Foundation of Korea . Publisher Copyright: © 2016 Elsevier Ltd Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2017/1/13

Y1 - 2017/1/13

N2 - An in-depth examination of the self-healing properties of both dienophile and diene functionalized ladder-like structured polysilsesquioxane copolymers and terpolymers was investigated. Through functionalization of both diene and dienophile on the double-stranded siloxane backbone with ternary n-alkyl functional groups acting as chain mobility control, the effect of chain mobility and chemical structure on self-healing and mechanical properties were elucidated. All of the single component self-healing hybrid materials exhibited fast healing times (∼5 min), and their de-crosslinked adducts exhibited exceptional retention of solubility in common organic solvents for good reusability, all while having inherent high thermal stability and optical transparency.

AB - An in-depth examination of the self-healing properties of both dienophile and diene functionalized ladder-like structured polysilsesquioxane copolymers and terpolymers was investigated. Through functionalization of both diene and dienophile on the double-stranded siloxane backbone with ternary n-alkyl functional groups acting as chain mobility control, the effect of chain mobility and chemical structure on self-healing and mechanical properties were elucidated. All of the single component self-healing hybrid materials exhibited fast healing times (∼5 min), and their de-crosslinked adducts exhibited exceptional retention of solubility in common organic solvents for good reusability, all while having inherent high thermal stability and optical transparency.

KW - Diels-Alder chemistry

KW - Self-healing polymers

KW - Silsesquioxane

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JF - Polymer

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Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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