Thermodynamic Calculation of Bi–Sn Alloy Phase Diagram Under Pressure with Advanced Density Measurements

Han Gyeol Kim; Joonho Lee; Guy Makov

doi:10.1007/s12540-019-00359-3

Thermodynamic Calculation of Bi–Sn Alloy Phase Diagram Under Pressure with Advanced Density Measurements

Han Gyeol Kim, Joonho Lee, Guy Makov

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Abstract: Bi–Sn alloy phase diagram under pressure was re-calculated using the CALculation of PHAse Diagrams method by applying new density data. Theoretically, alloy phase diagram under pressure can be calculated with bulk thermodynamic database and thermophysical property data such as density and sonic velocity. In the recent study by Emuna et al. (J Alloys Compd 687:360–369, 2016), thermodynamic parameters were determined from literature values with additional modification to fit experimental data of phase boundaries. In this study, density of liquid Bi–Sn alloys was re-evaluated with an advanced density measurement technique: the constrained drop method. By applying the new density data, the Bi–Sn phase diagram under pressure could be calculated successfully without any modification of thermodynamic parameters. Graphic Abstract: [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	586-590
Number of pages	5
Journal	Metals and Materials International
Volume	26
Issue number	5
DOIs	https://doi.org/10.1007/s12540-019-00359-3
Publication status	Published - 2020 May 1

Bibliographical note

Funding Information:
This work was supported by the Korea–Israel Joint Research Program—Nano & Pressure Phase Diagram of Alloys (NADIA), by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (MSIT) (NRF–2016K1A3A1A31913031) and by a grant from the Ministry of Science, Technology & Space, Israel.

Funding Information:
This work was supported by the Korea?Israel Joint Research Program?Nano & Pressure Phase Diagram of Alloys (NADIA), by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (MSIT) (NRF?2016K1A3A1A31913031) and by a grant from the Ministry of Science, Technology & Space, Israel.

Publisher Copyright:
© 2019, The Korean Institute of Metals and Materials.

Keywords

Bi–Sn alloy
CALPHAD
Density
Phase diagrams
Pressure

ASJC Scopus subject areas

Condensed Matter Physics
Mechanics of Materials
Metals and Alloys
Materials Chemistry

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10.1007/s12540-019-00359-3

Cite this

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title = "Thermodynamic Calculation of Bi–Sn Alloy Phase Diagram Under Pressure with Advanced Density Measurements",

abstract = "Abstract: Bi–Sn alloy phase diagram under pressure was re-calculated using the CALculation of PHAse Diagrams method by applying new density data. Theoretically, alloy phase diagram under pressure can be calculated with bulk thermodynamic database and thermophysical property data such as density and sonic velocity. In the recent study by Emuna et al. (J Alloys Compd 687:360–369, 2016), thermodynamic parameters were determined from literature values with additional modification to fit experimental data of phase boundaries. In this study, density of liquid Bi–Sn alloys was re-evaluated with an advanced density measurement technique: the constrained drop method. By applying the new density data, the Bi–Sn phase diagram under pressure could be calculated successfully without any modification of thermodynamic parameters. Graphic Abstract: [Figure not available: see fulltext.].",

keywords = "Bi–Sn alloy, CALPHAD, Density, Phase diagrams, Pressure",

author = "Kim, {Han Gyeol} and Joonho Lee and Guy Makov",

note = "Funding Information: This work was supported by the Korea–Israel Joint Research Program—Nano & Pressure Phase Diagram of Alloys (NADIA), by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (MSIT) (NRF–2016K1A3A1A31913031) and by a grant from the Ministry of Science, Technology & Space, Israel. Funding Information: This work was supported by the Korea?Israel Joint Research Program?Nano & Pressure Phase Diagram of Alloys (NADIA), by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (MSIT) (NRF?2016K1A3A1A31913031) and by a grant from the Ministry of Science, Technology & Space, Israel. Publisher Copyright: {\textcopyright} 2019, The Korean Institute of Metals and Materials.",

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doi = "10.1007/s12540-019-00359-3",

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AU - Kim, Han Gyeol

AU - Lee, Joonho

AU - Makov, Guy

N1 - Funding Information: This work was supported by the Korea–Israel Joint Research Program—Nano & Pressure Phase Diagram of Alloys (NADIA), by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (MSIT) (NRF–2016K1A3A1A31913031) and by a grant from the Ministry of Science, Technology & Space, Israel. Funding Information: This work was supported by the Korea?Israel Joint Research Program?Nano & Pressure Phase Diagram of Alloys (NADIA), by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (MSIT) (NRF?2016K1A3A1A31913031) and by a grant from the Ministry of Science, Technology & Space, Israel. Publisher Copyright: © 2019, The Korean Institute of Metals and Materials.

PY - 2020/5/1

Y1 - 2020/5/1

N2 - Abstract: Bi–Sn alloy phase diagram under pressure was re-calculated using the CALculation of PHAse Diagrams method by applying new density data. Theoretically, alloy phase diagram under pressure can be calculated with bulk thermodynamic database and thermophysical property data such as density and sonic velocity. In the recent study by Emuna et al. (J Alloys Compd 687:360–369, 2016), thermodynamic parameters were determined from literature values with additional modification to fit experimental data of phase boundaries. In this study, density of liquid Bi–Sn alloys was re-evaluated with an advanced density measurement technique: the constrained drop method. By applying the new density data, the Bi–Sn phase diagram under pressure could be calculated successfully without any modification of thermodynamic parameters. Graphic Abstract: [Figure not available: see fulltext.].

AB - Abstract: Bi–Sn alloy phase diagram under pressure was re-calculated using the CALculation of PHAse Diagrams method by applying new density data. Theoretically, alloy phase diagram under pressure can be calculated with bulk thermodynamic database and thermophysical property data such as density and sonic velocity. In the recent study by Emuna et al. (J Alloys Compd 687:360–369, 2016), thermodynamic parameters were determined from literature values with additional modification to fit experimental data of phase boundaries. In this study, density of liquid Bi–Sn alloys was re-evaluated with an advanced density measurement technique: the constrained drop method. By applying the new density data, the Bi–Sn phase diagram under pressure could be calculated successfully without any modification of thermodynamic parameters. Graphic Abstract: [Figure not available: see fulltext.].

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KW - Pressure

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Thermodynamic Calculation of Bi–Sn Alloy Phase Diagram Under Pressure with Advanced Density Measurements

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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