Thin Films of Highly Planar Semiconductor Polymers Exhibiting Band-like Transport at Room Temperature

Jiyoul Lee; Jong Won Chung; Do Hwan Kim; Bang Lin Lee; Jeong Il Park; Sangyoon Lee; Roger Häusermann; Bertram Batlogg; Sang Soo Lee; Insil Choi; Il Won Kim; Moon Sung Kang

doi:10.1021/jacs.5b04253

Thin Films of Highly Planar Semiconductor Polymers Exhibiting Band-like Transport at Room Temperature

Jiyoul Lee, Jong Won Chung, Do Hwan Kim, Bang Lin Lee, Jeong Il Park, Sangyoon Lee, Roger Häusermann, Bertram Batlogg, Sang Soo Lee, Insil Choi, Il Won Kim, Moon Sung Kang

KU-KIST Graduate School of Converging Science and Technology

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

We report the observation of band-like transport from printed polymer thin films at room temperature. This was achieved from donor-acceptor type thiophene-thiazole copolymer that was carefully designed to enhance the planarity of the backbone and the resulting transfer integral between the macromolecules. Due to the strong molecular interaction, the printed polymer film exhibited extremely low trap density comparable to that of molecular single crystals. Moreover, the energy barrier height for charge transport could be readily reduced with the aid of electric field, which led formation of extended electron states for band-like charge transport at room temperature.

Original language	English
Pages (from-to)	7990-7993
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	25
DOIs	https://doi.org/10.1021/jacs.5b04253
Publication status	Published - 2015 Jul 1

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.5b04253

Cite this

@article{4c59830b86e34a5b83d76a4e97166a2c,

title = "Thin Films of Highly Planar Semiconductor Polymers Exhibiting Band-like Transport at Room Temperature",

abstract = "We report the observation of band-like transport from printed polymer thin films at room temperature. This was achieved from donor-acceptor type thiophene-thiazole copolymer that was carefully designed to enhance the planarity of the backbone and the resulting transfer integral between the macromolecules. Due to the strong molecular interaction, the printed polymer film exhibited extremely low trap density comparable to that of molecular single crystals. Moreover, the energy barrier height for charge transport could be readily reduced with the aid of electric field, which led formation of extended electron states for band-like charge transport at room temperature.",

author = "Jiyoul Lee and Chung, {Jong Won} and Kim, {Do Hwan} and Lee, {Bang Lin} and Park, {Jeong Il} and Sangyoon Lee and Roger H{\"a}usermann and Bertram Batlogg and Lee, {Sang Soo} and Insil Choi and Kim, {Il Won} and Kang, {Moon Sung}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = jul,

day = "1",

doi = "10.1021/jacs.5b04253",

language = "English",

volume = "137",

pages = "7990--7993",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "25",

}

TY - JOUR

T1 - Thin Films of Highly Planar Semiconductor Polymers Exhibiting Band-like Transport at Room Temperature

AU - Lee, Jiyoul

AU - Chung, Jong Won

AU - Kim, Do Hwan

AU - Lee, Bang Lin

AU - Park, Jeong Il

AU - Lee, Sangyoon

AU - Häusermann, Roger

AU - Batlogg, Bertram

AU - Lee, Sang Soo

AU - Choi, Insil

AU - Kim, Il Won

AU - Kang, Moon Sung

PY - 2015/7/1

Y1 - 2015/7/1

N2 - We report the observation of band-like transport from printed polymer thin films at room temperature. This was achieved from donor-acceptor type thiophene-thiazole copolymer that was carefully designed to enhance the planarity of the backbone and the resulting transfer integral between the macromolecules. Due to the strong molecular interaction, the printed polymer film exhibited extremely low trap density comparable to that of molecular single crystals. Moreover, the energy barrier height for charge transport could be readily reduced with the aid of electric field, which led formation of extended electron states for band-like charge transport at room temperature.

AB - We report the observation of band-like transport from printed polymer thin films at room temperature. This was achieved from donor-acceptor type thiophene-thiazole copolymer that was carefully designed to enhance the planarity of the backbone and the resulting transfer integral between the macromolecules. Due to the strong molecular interaction, the printed polymer film exhibited extremely low trap density comparable to that of molecular single crystals. Moreover, the energy barrier height for charge transport could be readily reduced with the aid of electric field, which led formation of extended electron states for band-like charge transport at room temperature.

UR - http://www.scopus.com/inward/record.url?scp=84935047067&partnerID=8YFLogxK

U2 - 10.1021/jacs.5b04253

DO - 10.1021/jacs.5b04253

M3 - Article

AN - SCOPUS:84935047067

SN - 0002-7863

VL - 137

SP - 7990

EP - 7993

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 25

ER -

Thin Films of Highly Planar Semiconductor Polymers Exhibiting Band-like Transport at Room Temperature

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this