Abstract
New monomeric titanatranes {A figure is presented} (Ar = 2,6-di-i-Pr-phenyl; x = 0, 5; x = 1, 6; x = 2, 7; x = 3, 8) were synthesized from the corresponding tetradentate ligands 1-4, respectively, using an equimolar mixture of Ti(O-i-Pr)4 and 2,6-di-i-Pr-phenol. These compounds show the catalytic activity for the ring opening polymerization of l-lactide.
Original language | English |
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Pages (from-to) | 3519-3525 |
Number of pages | 7 |
Journal | Journal of Organometallic Chemistry |
Volume | 692 |
Issue number | 16 |
DOIs | |
Publication status | Published - 2007 Jul 15 |
Keywords
- Polylactide
- Ring opening polymerization
- Tetradentate ligand
- Titanium
- X-ray structure
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry