Toxicity identification and reduction of wastewaters from a pigment manufacturing factory

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    Abstract

    In this study, major toxicants in pigment wastewaters (i.e. raw wastewater and effluent) were determined by toxicity identification evaluations (TIEs), and changes in their toxicities due to combined gamma-ray (γ-ray) and ozone treatments were evaluated. From TIE results using Daphnia magna, Cr(VI) and o-toluidine were identified as major toxicants in the raw wastewater with concentrations of 2.47 and 25.3 mg l-1, respectively. This was confirmed by subsequent spiking and mass balance approaches. For effluent, TIE results suggested that organic anions were likely responsible for the observed toxicities. Toxicity reduction tests showed that γ-rays with ozone treatment after coagulation was more efficient in reducing toxicities in the raw wastewater (3.9-2.0 TU) than γ-ray treatment alone (3.9-3.1 TU). For pigment effluent, γ-ray/O3 treatment resulted in a complete removal of the acute toxicity.

    Original languageEnglish
    Pages (from-to)949-957
    Number of pages9
    JournalChemosphere
    Volume70
    Issue number6
    DOIs
    Publication statusPublished - 2008 Jan

    Bibliographical note

    Funding Information:
    This work was supported by a grant from the Basic Research Program of the Korea Science & Engineering Foundation (Grant No. R01-2005-000-10317-0).

    Keywords

    • Chromium
    • Daphnia magna
    • Gamma-rays
    • TIE
    • TRE
    • o-Toluidine

    ASJC Scopus subject areas

    • Environmental Engineering
    • Environmental Chemistry
    • General Chemistry
    • Pollution
    • Health, Toxicology and Mutagenesis

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