Electrochemical CO2 reduction is typically operated under highly refined electrolyte conditions. However, trace amounts of metal impurities exist even in ultrapure electrolyte solutions, causing a fatal deactivation of the catalysts. To address this issue, various efforts have been made to prevent the harmful deposition of metal impurities on the catalyst. Herein, we designed a new system where metal impurities are utilized as activators. We demonstrated "self-activation" of the N-doped carbon catalyst in the presence of Fe impurity with remarkable stability for 120 h. The origin of the self-activation was the selective adsorption of Fe impurity forming highly dispersed Fe sites through Fe-N interactions. The correlations between the self-activation and number of N sites and their moieties were investigated and further generalized into other metals, such as Ni, Zn, and Cu. This novel general strategy has enormous impact on design of durable catalysts for various electrochemical reactions suffering from deactivation by metal impurities.
Bibliographical noteFunding Information:
This work was supported by the program of the Korea Institute of Science and Technology (KIST) and Yonsei-KIST Convergence Research Program. It was partially supported by National Research Foundation (NRF) funded by the Korean government (No. 2019R1A2C2005521). Experiments at PLS-II were supported in part by MSICT and POSTECH.
© 2019 American Chemical Society.
ASJC Scopus subject areas
- Chemistry (miscellaneous)
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Energy Engineering and Power Technology
- Materials Chemistry