Two homochiral bimetallic metal-organic frameworks composed of a paramagnetic metalloligand and chiral camphorates: Multifunctional properties of sorption, magnetism, and enantioselective separation

Dae Won Ryu; Woo Ram Lee; Kwang Soo Lim; Won Ju Phang; Chang Seop Hong

doi:10.1021/cg501332u

Two homochiral bimetallic metal-organic frameworks composed of a paramagnetic metalloligand and chiral camphorates: Multifunctional properties of sorption, magnetism, and enantioselective separation

Dae Won Ryu
, Woo Ram Lee
, Kwang Soo Lim
, Won Ju Phang
, Chang Seop Hong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Two porous metal-organic frameworks [Co(Tt)₂][Cu₄(D-cam)₄]·5H₂O·DMF (1; Tt = tris(triazolyl)borate, D-H₂cam = d-(+)-camphoric acid or (1R,3S)-1,2,2-trimethyl-1,3-cyclopentanedicarboxylic acid) and [Co(Tt)₂][Cu₄(L-cam)₄]·5H₂O·2DMF (2; L-H₂cam = l-(-)-camphoric acid or (1S,3R)-1,2,2-trimethyl-1,3-cyclopentanedicarboxylic acid) were prepared by mixing Cu²⁺, Co(Tt), and camphoric acid under solvothermal conditions. The structures of 1 and 2 reveal that the two-dimensional layers composed of chiral ligands and Cu-Cu paddlewheel units are connected through the metalloligands to form three-dimensional networks. It is noted that these solids show multifunctional properties such as gas adsorption onto the pores of the frameworks, antiferromagnetic coupling between spin carriers, and a small enantioselective separation of racemic alcohols.

Original language	English
Pages (from-to)	6472-6477
Number of pages	6
Journal	Crystal Growth and Design
Volume	14
Issue number	12
DOIs	https://doi.org/10.1021/cg501332u
Publication status	Published - 2014 Dec 3

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Publisher Copyright:
© 2014 American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/cg501332u

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Two homochiral bimetallic metal-organic frameworks composed of a paramagnetic metalloligand and chiral camphorates: Multifunctional properties of sorption, magnetism, and enantioselective separation. / Ryu, Dae Won; Lee, Woo Ram; Lim, Kwang Soo et al.
In: Crystal Growth and Design, Vol. 14, No. 12, 03.12.2014, p. 6472-6477.

Research output: Contribution to journal › Article › peer-review

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abstract = "Two porous metal-organic frameworks [Co(Tt)2][Cu4(D-cam)4]·5H2O·DMF (1; Tt = tris(triazolyl)borate, D-H2cam = d-(+)-camphoric acid or (1R,3S)-1,2,2-trimethyl-1,3-cyclopentanedicarboxylic acid) and [Co(Tt)2][Cu4(L-cam)4]·5H2O·2DMF (2; L-H2cam = l-(-)-camphoric acid or (1S,3R)-1,2,2-trimethyl-1,3-cyclopentanedicarboxylic acid) were prepared by mixing Cu2+, Co(Tt), and camphoric acid under solvothermal conditions. The structures of 1 and 2 reveal that the two-dimensional layers composed of chiral ligands and Cu-Cu paddlewheel units are connected through the metalloligands to form three-dimensional networks. It is noted that these solids show multifunctional properties such as gas adsorption onto the pores of the frameworks, antiferromagnetic coupling between spin carriers, and a small enantioselective separation of racemic alcohols.",

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Two homochiral bimetallic metal-organic frameworks composed of a paramagnetic metalloligand and chiral camphorates: Multifunctional properties of sorption, magnetism, and enantioselective separation

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