Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Sik Yoo Houng, Il Kim Jae, Namgeun Yang, Kwan Koh Eui, Je Geun Park, Seop Hong Chang

    Research output: Contribution to journalArticlepeer-review

    53 Citations (Scopus)

    Abstract

    A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N 3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

    Original languageEnglish
    Pages (from-to)9054-9056
    Number of pages3
    JournalInorganic Chemistry
    Volume46
    Issue number22
    DOIs
    Publication statusPublished - 2007 Oct 29

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

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