Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Sik Yoo Houng; Il Kim Jae; Namgeun Yang; Kwan Koh Eui; Je Geun Park; Seop Hong Chang

doi:10.1021/ic7014995

Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Sik Yoo Houng, Il Kim Jae, Namgeun Yang, Kwan Koh Eui, Je Geun Park, Seop Hong Chang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N ₃)₂]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

Original language	English
Pages (from-to)	9054-9056
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	22
DOIs	https://doi.org/10.1021/ic7014995
Publication status	Published - 2007 Oct 29

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic7014995

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abstract = "A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N 3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.",

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AU - Yang, Namgeun

AU - Eui, Kwan Koh

AU - Park, Je Geun

AU - Chang, Seop Hong

PY - 2007/10/29

Y1 - 2007/10/29

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AB - A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N 3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

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Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Abstract

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