Unusual Regiospecificity in Syn Elimination from trans-2-Chloro-3-fluoro-2,3-dihydrobenzofuran Promoted by Complex Base

Richard A. Bartsch; Bong Rae Cho; Michael J. Pugia

doi:10.1021/jo00233a046

Unusual Regiospecificity in Syn Elimination from trans-2-Chloro-3-fluoro-2,3-dihydrobenzofuran Promoted by Complex Base

Richard A. Bartsch, Bong Rae Cho, Michael J. Pugia

* Honorary professors

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Elimination from trans-2-chloro-3-fluoro-2,3-dihydrobenzofuran induced by NaNH₂-NaO-t-Bu in THF results in syn dehydrofluorination to the exclusion of β-aryl-activated syn dehydrochlorination.

Original language	English
Pages (from-to)	5494
Number of pages	1
Journal	Journal of Organic Chemistry
Volume	52
Issue number	24
DOIs	https://doi.org/10.1021/jo00233a046
Publication status	Published - 1987 Nov 1

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo00233a046

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@article{e842f49af59f4d6c8d10d588e1326b50,

title = "Unusual Regiospecificity in Syn Elimination from trans-2-Chloro-3-fluoro-2,3-dihydrobenzofuran Promoted by Complex Base",

abstract = "Elimination from trans-2-chloro-3-fluoro-2,3-dihydrobenzofuran induced by NaNH2-NaO-t-Bu in THF results in syn dehydrofluorination to the exclusion of β-aryl-activated syn dehydrochlorination.",

author = "Bartsch, {Richard A.} and Cho, {Bong Rae} and Pugia, {Michael J.}",

year = "1987",

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doi = "10.1021/jo00233a046",

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volume = "52",

pages = "5494",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Unusual Regiospecificity in Syn Elimination from trans-2-Chloro-3-fluoro-2,3-dihydrobenzofuran Promoted by Complex Base

AU - Bartsch, Richard A.

AU - Cho, Bong Rae

AU - Pugia, Michael J.

PY - 1987/11/1

Y1 - 1987/11/1

N2 - Elimination from trans-2-chloro-3-fluoro-2,3-dihydrobenzofuran induced by NaNH2-NaO-t-Bu in THF results in syn dehydrofluorination to the exclusion of β-aryl-activated syn dehydrochlorination.

AB - Elimination from trans-2-chloro-3-fluoro-2,3-dihydrobenzofuran induced by NaNH2-NaO-t-Bu in THF results in syn dehydrofluorination to the exclusion of β-aryl-activated syn dehydrochlorination.

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U2 - 10.1021/jo00233a046

DO - 10.1021/jo00233a046

M3 - Article

AN - SCOPUS:33845281439

SN - 0022-3263

VL - 52

SP - 5494

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 24

ER -

Unusual Regiospecificity in Syn Elimination from trans-2-Chloro-3-fluoro-2,3-dihydrobenzofuran Promoted by Complex Base

Abstract

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