Abstract
The electrochemical properties of thiacalix[4]arene (TCA) and p-tert-butylthiacalix[4]arene (BuTCA) in the presence of various metal ions were investigated by voltammetry in organic and aqueous acetonitrile solution (pH 8). Their behavior were closely related to the complex formation by entrapping metal ions into the cavity of host molecules, and were compared with the results with calix[4]arenes. Thiacalix[4]arenes showed better binding ability towards transition metal ions than alkali or alkaline earth metal ions.
Original language | English |
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Pages (from-to) | 3759-3763 |
Number of pages | 5 |
Journal | Electrochimica Acta |
Volume | 49 |
Issue number | 22-23 SPEC. ISS. |
DOIs | |
Publication status | Published - 2004 Sept 15 |
Externally published | Yes |
Bibliographical note
Funding Information:This work was supported in part by grant no. 1999-2-121-001-5 from the Basic Research Program of the Korea Science and Engineering Foundation, by the Brain Korea 21 as student fellowship (THK) and Center for Molecular Catalysts, Seoul National University.
Keywords
- Calixarene
- Cation recognition
- Thiacalixarene
- Transition metal ion
- Voltammetry
ASJC Scopus subject areas
- General Chemical Engineering
- Electrochemistry