Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application

Tae Hyun Kim; Jae Kwang Lee; Ju Han Bok; Jong Seung Kim; Hasuck Kim

doi:10.1016/j.electacta.2004.02.049

Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application

Tae Hyun Kim, Jae Kwang Lee, Ju Han Bok, Jong Seung Kim, Hasuck Kim

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The electrochemical properties of thiacalix[4]arene (TCA) and p-tert-butylthiacalix[4]arene (BuTCA) in the presence of various metal ions were investigated by voltammetry in organic and aqueous acetonitrile solution (pH 8). Their behavior were closely related to the complex formation by entrapping metal ions into the cavity of host molecules, and were compared with the results with calix[4]arenes. Thiacalix[4]arenes showed better binding ability towards transition metal ions than alkali or alkaline earth metal ions.

Original language	English
Pages (from-to)	3759-3763
Number of pages	5
Journal	Electrochimica Acta
Volume	49
Issue number	22-23 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.electacta.2004.02.049
Publication status	Published - 2004 Sept 15
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported in part by grant no. 1999-2-121-001-5 from the Basic Research Program of the Korea Science and Engineering Foundation, by the Brain Korea 21 as student fellowship (THK) and Center for Molecular Catalysts, Seoul National University.

Keywords

Calixarene
Cation recognition
Thiacalixarene
Transition metal ion
Voltammetry

ASJC Scopus subject areas

General Chemical Engineering
Electrochemistry

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10.1016/j.electacta.2004.02.049

Cite this

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title = "Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application",

abstract = "The electrochemical properties of thiacalix[4]arene (TCA) and p-tert-butylthiacalix[4]arene (BuTCA) in the presence of various metal ions were investigated by voltammetry in organic and aqueous acetonitrile solution (pH 8). Their behavior were closely related to the complex formation by entrapping metal ions into the cavity of host molecules, and were compared with the results with calix[4]arenes. Thiacalix[4]arenes showed better binding ability towards transition metal ions than alkali or alkaline earth metal ions.",

keywords = "Calixarene, Cation recognition, Thiacalixarene, Transition metal ion, Voltammetry",

author = "Kim, {Tae Hyun} and Lee, {Jae Kwang} and Bok, {Ju Han} and Kim, {Jong Seung} and Hasuck Kim",

note = "Funding Information: This work was supported in part by grant no. 1999-2-121-001-5 from the Basic Research Program of the Korea Science and Engineering Foundation, by the Brain Korea 21 as student fellowship (THK) and Center for Molecular Catalysts, Seoul National University. ",

year = "2004",

month = sep,

day = "15",

doi = "10.1016/j.electacta.2004.02.049",

language = "English",

volume = "49",

pages = "3759--3763",

journal = "Electrochimica Acta",

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number = "22-23 SPEC. ISS.",

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T1 - Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application

AU - Kim, Tae Hyun

AU - Lee, Jae Kwang

AU - Bok, Ju Han

AU - Kim, Jong Seung

AU - Kim, Hasuck

N1 - Funding Information: This work was supported in part by grant no. 1999-2-121-001-5 from the Basic Research Program of the Korea Science and Engineering Foundation, by the Brain Korea 21 as student fellowship (THK) and Center for Molecular Catalysts, Seoul National University.

PY - 2004/9/15

Y1 - 2004/9/15

N2 - The electrochemical properties of thiacalix[4]arene (TCA) and p-tert-butylthiacalix[4]arene (BuTCA) in the presence of various metal ions were investigated by voltammetry in organic and aqueous acetonitrile solution (pH 8). Their behavior were closely related to the complex formation by entrapping metal ions into the cavity of host molecules, and were compared with the results with calix[4]arenes. Thiacalix[4]arenes showed better binding ability towards transition metal ions than alkali or alkaline earth metal ions.

AB - The electrochemical properties of thiacalix[4]arene (TCA) and p-tert-butylthiacalix[4]arene (BuTCA) in the presence of various metal ions were investigated by voltammetry in organic and aqueous acetonitrile solution (pH 8). Their behavior were closely related to the complex formation by entrapping metal ions into the cavity of host molecules, and were compared with the results with calix[4]arenes. Thiacalix[4]arenes showed better binding ability towards transition metal ions than alkali or alkaline earth metal ions.

KW - Calixarene

KW - Cation recognition

KW - Thiacalixarene

KW - Transition metal ion

KW - Voltammetry

UR - http://www.scopus.com/inward/record.url?scp=3042812498&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2004.02.049

DO - 10.1016/j.electacta.2004.02.049

M3 - Article

AN - SCOPUS:3042812498

SN - 0013-4686

VL - 49

SP - 3759

EP - 3763

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 22-23 SPEC. ISS.

ER -

Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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