Water-soluble two-photon fluorophores based on paracyclophane

Han Young Woo; Guillermo C. Bazan

doi:10.1080/15421400801925075

Water-soluble two-photon fluorophores based on paracyclophane

Han Young Woo, Guillermo C. Bazan

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We report the synthesis, linear and nonlinear spectroscopy of the paracyclophane-based two-photon absorption (TPA) fluorophores. Two-photon induced fluorescence (TPIF) measurements in water show a substantial decrease in TPA cross section () and fluorescence quantum yield (), relative to toluene. We note that to obtain optimum two-photon action cross sections () in water, one needs to fine tune the intramolecular charge transfer (ICT). Microenvironment modulation using the micellar structure in water increases values similar to those obtained in toluene. The measured values in water are the highest among reported so far, suggesting important guidelines for designing of optimized TPIF molecular-labels.

Original language	English
Pages (from-to)	928-933
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals
Volume	485
DOIs	https://doi.org/10.1080/15421400801925075
Publication status	Published - 2008
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD, Basic Research Promotion Fund) (KRF-2006-331-D00139).

Keywords

Bioimaging
Paracyclophane
TPA molecular label
Two-photon absorption

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1080/15421400801925075

Cite this

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title = "Water-soluble two-photon fluorophores based on paracyclophane",

abstract = "We report the synthesis, linear and nonlinear spectroscopy of the paracyclophane-based two-photon absorption (TPA) fluorophores. Two-photon induced fluorescence (TPIF) measurements in water show a substantial decrease in TPA cross section () and fluorescence quantum yield (), relative to toluene. We note that to obtain optimum two-photon action cross sections () in water, one needs to fine tune the intramolecular charge transfer (ICT). Microenvironment modulation using the micellar structure in water increases values similar to those obtained in toluene. The measured values in water are the highest among reported so far, suggesting important guidelines for designing of optimized TPIF molecular-labels.",

keywords = "Bioimaging, Paracyclophane, TPA molecular label, Two-photon absorption",

author = "Woo, {Han Young} and Bazan, {Guillermo C.}",

note = "Funding Information: This work was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD, Basic Research Promotion Fund) (KRF-2006-331-D00139).",

year = "2008",

doi = "10.1080/15421400801925075",

language = "English",

volume = "485",

pages = "928--933",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

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T1 - Water-soluble two-photon fluorophores based on paracyclophane

AU - Woo, Han Young

AU - Bazan, Guillermo C.

N1 - Funding Information: This work was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD, Basic Research Promotion Fund) (KRF-2006-331-D00139).

PY - 2008

Y1 - 2008

N2 - We report the synthesis, linear and nonlinear spectroscopy of the paracyclophane-based two-photon absorption (TPA) fluorophores. Two-photon induced fluorescence (TPIF) measurements in water show a substantial decrease in TPA cross section () and fluorescence quantum yield (), relative to toluene. We note that to obtain optimum two-photon action cross sections () in water, one needs to fine tune the intramolecular charge transfer (ICT). Microenvironment modulation using the micellar structure in water increases values similar to those obtained in toluene. The measured values in water are the highest among reported so far, suggesting important guidelines for designing of optimized TPIF molecular-labels.

AB - We report the synthesis, linear and nonlinear spectroscopy of the paracyclophane-based two-photon absorption (TPA) fluorophores. Two-photon induced fluorescence (TPIF) measurements in water show a substantial decrease in TPA cross section () and fluorescence quantum yield (), relative to toluene. We note that to obtain optimum two-photon action cross sections () in water, one needs to fine tune the intramolecular charge transfer (ICT). Microenvironment modulation using the micellar structure in water increases values similar to those obtained in toluene. The measured values in water are the highest among reported so far, suggesting important guidelines for designing of optimized TPIF molecular-labels.

KW - Bioimaging

KW - Paracyclophane

KW - TPA molecular label

KW - Two-photon absorption

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U2 - 10.1080/15421400801925075

DO - 10.1080/15421400801925075

M3 - Article

AN - SCOPUS:47549111720

SN - 1542-1406

VL - 485

SP - 928

EP - 933

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

Water-soluble two-photon fluorophores based on paracyclophane

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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