Abstract
A dense yttria stabilized zirconia (YSZ)-carbonate membrane that was impermeable to gas at low temperature became highly permeable to CO2 at temperature above the melting point of the carbonate. The CO2 permeance across the YSZ-molten carbonate dual-phase membrane was observed to be higher than 0.1×10-8mol/m2/Pa/s at temperature >650°C. The movement of ions was promoted at high temperature as YSZ and molten carbonate became highly conductive to oxygen ions and carbonate species, respectively. Addition of poly(methyl methacrylate) (PMMA) during preparation of macroporous YSZ support created interconnected pore structures that were found conducive for carbonate infiltration and integration with the membrane materials.
Original language | English |
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Pages (from-to) | 3703-3708 |
Number of pages | 6 |
Journal | Journal of Industrial and Engineering Chemistry |
Volume | 20 |
Issue number | 5 |
DOIs | |
Publication status | Published - 2014 Sept 25 |
Bibliographical note
Funding Information:This research was supported by Korea Institute of Science and Technology .
Keywords
- Carbon dioxide
- Membrane
- Molten carbonate
- Permeability
- YSZ
ASJC Scopus subject areas
- General Chemical Engineering